Simple oxazolidine chiral diene ligands for enantioselective rh-catalyzed conjugate additions

N.W.G. Fairhurst, R.H. Munday, D.R. Carbery

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Abstract

Simple oxazolidine-based chiral diene ligands, ultimately derived from serine, have been synthesized using the Seebach self-regeneration of stereocenters strategy. The ligands have been used in the enantioselective Rh-catalyzed conjugate addition of aryl boronic acids to cyclohexenone. An efficient 'in vacuo' reaction protocol has been developed as part of this study.
Original languageEnglish
Pages (from-to)496-498
Number of pages3
JournalSynlett
Volume24
Issue number4
Early online date23 Jan 2013
DOIs
Publication statusPublished - 2013

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