Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag2L2][BF4]2(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)

Edwin C. Constable; Muhammad S. Khan; Michael C. Liptrot; Jack Lewis; Paul R. Raithby

doi:10.1016/S0020-1693(00)85883-1

Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)

Edwin C. Constable, Muhammad S. Khan, Michael C. Liptrot, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Silver(I) ions do not act as templates for the formation of planar macrocyclic ligands based upon 2,2′-bipyridine or 1,10-phenanthroline, but incorporation of silver(I) into the performed macrocycles, obtained from transient template reactions, is facile. The complexes so obtained have a 1:1 ratio of silver to macrocycle. The crystal structure of the complex [Ag₂L₂][BF₄]₂ reveals a dimeric structure in the solid state with two distinct silver environments. Crystallographic data: space group P2₁/n, a=18.295(3), b=9.763(2), c=25.643(5) Å, β=105.03(1), V=4665 Å³, Z=4.

Original language	English
Pages (from-to)	239-244
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	179
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(00)85883-1
Publication status	Published - 15 Jan 1991

Funding

We thank the SERC for the award of a studentship (M.C.L.), the Royal Society and the Nuffield Foundation for a Fellowship (M.S.K.) and Dhaka University, Bangladesh for study leave (M.S.K.).

Funders	Funder number
The Nuffield Foundation
Royal Society
Engineering and Physical Sciences Research Council
University of Dhaka

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Constable, E. C., Khan, M. S., Liptrot, M. C., Lewis, J., & Raithby, P. R. (1991). Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). Inorganica Chimica Acta, 179(2), 239-244. https://doi.org/10.1016/S0020-1693(00)85883-1

Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). / Constable, Edwin C.; Khan, Muhammad S.; Liptrot, Michael C. et al.
In: Inorganica Chimica Acta, Vol. 179, No. 2, 15.01.1991, p. 239-244.

Research output: Contribution to journal › Article › peer-review

Constable, EC, Khan, MS, Liptrot, MC, Lewis, J & Raithby, PR 1991, 'Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)', Inorganica Chimica Acta, vol. 179, no. 2, pp. 239-244. https://doi.org/10.1016/S0020-1693(00)85883-1

Constable EC, Khan MS, Liptrot MC, Lewis J, Raithby PR. Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). Inorganica Chimica Acta. 1991 Jan 15;179(2):239-244. doi: 10.1016/S0020-1693(00)85883-1

Constable, Edwin C. ; Khan, Muhammad S. ; Liptrot, Michael C. et al. / Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag₂L₂][BF₄]₂(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene). In: Inorganica Chimica Acta. 1991 ; Vol. 179, No. 2. pp. 239-244.

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title = "Silver(I)-silver(I) interactions in complexes of pentadentate macrocyclic ligands; crystal and molecular structure of [Ag2L2][BF4]2(L1,11-bis(2′-hydroxyethyl)-4,8; 12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa-2,4,6,9,12,14,18,20-octaene)",

abstract = "Silver(I) ions do not act as templates for the formation of planar macrocyclic ligands based upon 2,2′-bipyridine or 1,10-phenanthroline, but incorporation of silver(I) into the performed macrocycles, obtained from transient template reactions, is facile. The complexes so obtained have a 1:1 ratio of silver to macrocycle. The crystal structure of the complex [Ag2L2][BF4]2 reveals a dimeric structure in the solid state with two distinct silver environments. Crystallographic data: space group P21/n, a=18.295(3), b=9.763(2), c=25.643(5) {\AA}, β=105.03(1), V=4665 {\AA}3, Z=4.",

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AB - Silver(I) ions do not act as templates for the formation of planar macrocyclic ligands based upon 2,2′-bipyridine or 1,10-phenanthroline, but incorporation of silver(I) into the performed macrocycles, obtained from transient template reactions, is facile. The complexes so obtained have a 1:1 ratio of silver to macrocycle. The crystal structure of the complex [Ag2L2][BF4]2 reveals a dimeric structure in the solid state with two distinct silver environments. Crystallographic data: space group P21/n, a=18.295(3), b=9.763(2), c=25.643(5) Å, β=105.03(1), V=4665 Å3, Z=4.

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