Silver(I) aryloxide-triphenylphosphine complexes. An assessment of their potential as CVD precursors and the structure of [Ag(OC6H4Me-2)(PPh3)(3)]center dot 2-MeC6H4OH center dot C6H5Me

D A Edwards, M F Mahon, K C Molloy, V Ogrodnik

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Abstract

The silver aryloxide-triphenylphoshine complexes [Ag(OR)(PPh3)(2)] (R = C6H2Cl3-2,4,6 (1), C6H4Me-2 (2) or C6H2(CH2NMe2)(3)-2,4,6 (3)) and [Ag(OR)(PPh3)(3)].ROH (R = Ph (4) or C6H4Me-2 (5)) have been prepared and characterised. Complexes 1, 3 and 5 were tested as precursors for the growth of silver films on glass substrates using an aerosol-assisted chemical vapour deposition method. Although films were produced, they were of poor quality compared to those produced from other silver complexes as precursors. A crystal structure determination of 5 as a toluene solvate shows the o-cresolato ligand to be monodentate and together with the triphenylphosphine ligands generates a distorted tetrahedral array around the silver. The additional o-cresol molecule is hydrogen-bonded to the o-cresolato oxygen atom and not directly bonded to silver. (C) 2003 Elsevier Science B.V. All rights reserved.
Original languageEnglish
Pages (from-to)37-44
Number of pages8
JournalInorganica Chimica Acta
Volume349
DOIs
Publication statusPublished - 2003

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Silver
Chemical vapor deposition
silver
vapor deposition
Ligands
cresols
ligands
Toluene
Aerosols
toluene
Hydrogen
oxygen atoms
aerosols
Crystal structure
triphenylphosphine
Oxygen
Glass
Atoms
crystal structure
Molecules

Cite this

@article{92a3269a355849e0ab7fed3557392cce,
title = "Silver(I) aryloxide-triphenylphosphine complexes. An assessment of their potential as CVD precursors and the structure of [Ag(OC6H4Me-2)(PPh3)(3)]center dot 2-MeC6H4OH center dot C6H5Me",
abstract = "The silver aryloxide-triphenylphoshine complexes [Ag(OR)(PPh3)(2)] (R = C6H2Cl3-2,4,6 (1), C6H4Me-2 (2) or C6H2(CH2NMe2)(3)-2,4,6 (3)) and [Ag(OR)(PPh3)(3)].ROH (R = Ph (4) or C6H4Me-2 (5)) have been prepared and characterised. Complexes 1, 3 and 5 were tested as precursors for the growth of silver films on glass substrates using an aerosol-assisted chemical vapour deposition method. Although films were produced, they were of poor quality compared to those produced from other silver complexes as precursors. A crystal structure determination of 5 as a toluene solvate shows the o-cresolato ligand to be monodentate and together with the triphenylphosphine ligands generates a distorted tetrahedral array around the silver. The additional o-cresol molecule is hydrogen-bonded to the o-cresolato oxygen atom and not directly bonded to silver. (C) 2003 Elsevier Science B.V. All rights reserved.",
author = "Edwards, {D A} and Mahon, {M F} and Molloy, {K C} and V Ogrodnik",
note = "ID number: ISI:000183673100006",
year = "2003",
doi = "10.1016/s0020-1693(03)00077-x",
language = "English",
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pages = "37--44",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

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TY - JOUR

T1 - Silver(I) aryloxide-triphenylphosphine complexes. An assessment of their potential as CVD precursors and the structure of [Ag(OC6H4Me-2)(PPh3)(3)]center dot 2-MeC6H4OH center dot C6H5Me

AU - Edwards, D A

AU - Mahon, M F

AU - Molloy, K C

AU - Ogrodnik, V

N1 - ID number: ISI:000183673100006

PY - 2003

Y1 - 2003

N2 - The silver aryloxide-triphenylphoshine complexes [Ag(OR)(PPh3)(2)] (R = C6H2Cl3-2,4,6 (1), C6H4Me-2 (2) or C6H2(CH2NMe2)(3)-2,4,6 (3)) and [Ag(OR)(PPh3)(3)].ROH (R = Ph (4) or C6H4Me-2 (5)) have been prepared and characterised. Complexes 1, 3 and 5 were tested as precursors for the growth of silver films on glass substrates using an aerosol-assisted chemical vapour deposition method. Although films were produced, they were of poor quality compared to those produced from other silver complexes as precursors. A crystal structure determination of 5 as a toluene solvate shows the o-cresolato ligand to be monodentate and together with the triphenylphosphine ligands generates a distorted tetrahedral array around the silver. The additional o-cresol molecule is hydrogen-bonded to the o-cresolato oxygen atom and not directly bonded to silver. (C) 2003 Elsevier Science B.V. All rights reserved.

AB - The silver aryloxide-triphenylphoshine complexes [Ag(OR)(PPh3)(2)] (R = C6H2Cl3-2,4,6 (1), C6H4Me-2 (2) or C6H2(CH2NMe2)(3)-2,4,6 (3)) and [Ag(OR)(PPh3)(3)].ROH (R = Ph (4) or C6H4Me-2 (5)) have been prepared and characterised. Complexes 1, 3 and 5 were tested as precursors for the growth of silver films on glass substrates using an aerosol-assisted chemical vapour deposition method. Although films were produced, they were of poor quality compared to those produced from other silver complexes as precursors. A crystal structure determination of 5 as a toluene solvate shows the o-cresolato ligand to be monodentate and together with the triphenylphosphine ligands generates a distorted tetrahedral array around the silver. The additional o-cresol molecule is hydrogen-bonded to the o-cresolato oxygen atom and not directly bonded to silver. (C) 2003 Elsevier Science B.V. All rights reserved.

U2 - 10.1016/s0020-1693(03)00077-x

DO - 10.1016/s0020-1693(03)00077-x

M3 - Article

VL - 349

SP - 37

EP - 44

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -