TY - JOUR
T1 - Self-supported paired electrosynthesis of 2,5-dimethoxy-2,5-dihydrofuran using a thin layer flow cell without intentionally added supporting electrolyte
AU - Horii, D
AU - Atobe, M
AU - Fuchigami, T
AU - Marken, F
N1 - ID number: ISI:000226157600008
PY - 2005
Y1 - 2005
N2 - 2,5-Dimethoxy-2,5-dihydrofuran was prepared by the oxidation of furan and by the reduction of methanol solvent using a thin layer flow cell geometry with anode and cathode directly facing each other and without intentionally added electrolyte. Controlling factors for this kind of self-supported paired electrosynthesis, such as the electrode material, the current density, and the flow rate were optimized. The maximum chemical yield of 98% of pure product without work-up could be obtained with a combination of a glassy carbon anode and a platinum cathode in a single pass of furan solution. (C) 2004 Elsevier B.V. All rights reserved.
AB - 2,5-Dimethoxy-2,5-dihydrofuran was prepared by the oxidation of furan and by the reduction of methanol solvent using a thin layer flow cell geometry with anode and cathode directly facing each other and without intentionally added electrolyte. Controlling factors for this kind of self-supported paired electrosynthesis, such as the electrode material, the current density, and the flow rate were optimized. The maximum chemical yield of 98% of pure product without work-up could be obtained with a combination of a glassy carbon anode and a platinum cathode in a single pass of furan solution. (C) 2004 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.elecom.2004.10.012
DO - 10.1016/j.elecom.2004.10.012
M3 - Article
SN - 1388-2481
VL - 7
SP - 35
EP - 39
JO - Electrochemistry Communications
JF - Electrochemistry Communications
IS - 1
ER -