Self-assembled films formed at the air-water interface from CTAB/SDS mixtures with water-soluble polymers

Karen J Edler, Matthew J Wasbrough, James A Holdaway, B M D O'Driscoll

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

We have investigated the spontaneous self-assembly of solid, mesostructured films that form at the air-solution interface on solutions containing a neutral water-soluble polymer and catanionic surfactant mixtures of hexadecyltrimethylammonium bromide (CTAB) and sodium dodecylsulphate (SDS). The formation processes and structures were probed using neutron reflectivity, X-ray reflectivity, off-specular time-resolved scattering, and grazing incidence diffraction. The mesostructures of films prepared with polyethylene oxide, polyethylenimine, and polyacrylamide at various cationic/anionic surfactant molar ratios are compared. The results suggest that polymers having a weak interaction with the surfactants cause a depletion aggregation process that results in a lamellar phase, whereas polymers having a stronger interaction with the surfactants produce more complex mesostructures in the films.
Original languageEnglish
Pages (from-to)4047-4055
Number of pages9
JournalLangmuir
Volume25
Issue number7
Early online date18 Dec 2008
DOIs
Publication statusPublished - 7 Apr 2009

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