Selective oxidation of salicylic alcohol to aldehyde with O2/H2 using Au-Pd on titanate nanotubes catalysts

Laura Torrente-Murciano; Thomas Villager; David Chadwick

doi:10.1002/cctc.201403040

Selective oxidation of salicylic alcohol to aldehyde with O₂/H₂ using Au-Pd on titanate nanotubes catalysts

Laura Torrente-Murciano, Thomas Villager, David Chadwick

Imperial College London

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34 Citations (SciVal)

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Abstract

Alcohol oxidation with 100% selectivity to the aldehyde product (versus acid formation) is achieved at mild conditions by a tandem-type system where the intermediate species of hydrogen peroxide formation from an O₂/H₂ mixture are formed and utilised directly over Au-Pd/Ti-NT catalysts. Insitu reaction of the intermediate species minimises the parallel decomposition of hydrogen peroxide into water, overcoming one of the limitations on the use of hydrogen peroxide as a green oxidant. In the mix for selective oxidation: Insitu formation and utilisation of intermediate oxidising species from O₂/H₂ mixtures in a tandem-type system minimises the parallel decomposition of hydrogen peroxide with 100% selectivity to the aldehyde product.

Original language	English
Pages (from-to)	925-927
Journal	ChemCatChem
Volume	7
Issue number	6
Early online date	18 Feb 2015
DOIs	https://doi.org/10.1002/cctc.201403040
Publication status	Published - Mar 2015

Keywords

Gold
Hydrogen peroxide
Palladium
Selective oxidation
Tandem reactions

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10.1002/cctc.201403040

Selective oxidation of alcohols to aldehyde in tandem systems_ChemCatChem_revised_final_PUREAccepted author manuscript, 1.31 MB

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title = "Selective oxidation of salicylic alcohol to aldehyde with O2/H2 using Au-Pd on titanate nanotubes catalysts",

abstract = "Alcohol oxidation with 100\% selectivity to the aldehyde product (versus acid formation) is achieved at mild conditions by a tandem-type system where the intermediate species of hydrogen peroxide formation from an O2/H2 mixture are formed and utilised directly over Au-Pd/Ti-NT catalysts. Insitu reaction of the intermediate species minimises the parallel decomposition of hydrogen peroxide into water, overcoming one of the limitations on the use of hydrogen peroxide as a green oxidant. In the mix for selective oxidation: Insitu formation and utilisation of intermediate oxidising species from O2/H2 mixtures in a tandem-type system minimises the parallel decomposition of hydrogen peroxide with 100\% selectivity to the aldehyde product.",

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AU - Villager, Thomas

AU - Chadwick, David

PY - 2015/3

Y1 - 2015/3

N2 - Alcohol oxidation with 100% selectivity to the aldehyde product (versus acid formation) is achieved at mild conditions by a tandem-type system where the intermediate species of hydrogen peroxide formation from an O2/H2 mixture are formed and utilised directly over Au-Pd/Ti-NT catalysts. Insitu reaction of the intermediate species minimises the parallel decomposition of hydrogen peroxide into water, overcoming one of the limitations on the use of hydrogen peroxide as a green oxidant. In the mix for selective oxidation: Insitu formation and utilisation of intermediate oxidising species from O2/H2 mixtures in a tandem-type system minimises the parallel decomposition of hydrogen peroxide with 100% selectivity to the aldehyde product.

AB - Alcohol oxidation with 100% selectivity to the aldehyde product (versus acid formation) is achieved at mild conditions by a tandem-type system where the intermediate species of hydrogen peroxide formation from an O2/H2 mixture are formed and utilised directly over Au-Pd/Ti-NT catalysts. Insitu reaction of the intermediate species minimises the parallel decomposition of hydrogen peroxide into water, overcoming one of the limitations on the use of hydrogen peroxide as a green oxidant. In the mix for selective oxidation: Insitu formation and utilisation of intermediate oxidising species from O2/H2 mixtures in a tandem-type system minimises the parallel decomposition of hydrogen peroxide with 100% selectivity to the aldehyde product.

KW - Gold

KW - Hydrogen peroxide

KW - Palladium

KW - Selective oxidation

KW - Tandem reactions

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UR - http://dx.doi.org/10.1002/cctc.201403040

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DO - 10.1002/cctc.201403040

M3 - Article

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JO - ChemCatChem

JF - ChemCatChem

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ER -

Selective oxidation of salicylic alcohol to aldehyde with O₂/H₂ using Au-Pd on titanate nanotubes catalysts

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