Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks

Andrew D Burrows; Laura C Fisher; C Richardson; Sean P Rigby

doi:10.1039/c1cc10143a

Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks

Andrew D Burrows
, Laura C Fisher
, C Richardson
, Sean P Rigby

Research output: Contribution to journal › Article › peer-review

55 Citations (SciVal)

Abstract

Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn4O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.

Original language	English
Pages (from-to)	3380-3382
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	12
DOIs	https://doi.org/10.1039/c1cc10143a
Publication status	Published - 28 Mar 2011

Access to Document

10.1039/c1cc10143a

Cite this

@article{6c2688759d4a494daeceab619e158260,

title = "Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks",

abstract = "Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn4O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.",

author = "Burrows, \{Andrew D\} and Fisher, \{Laura C\} and C Richardson and Rigby, \{Sean P\}",

year = "2011",

month = mar,

day = "28",

doi = "10.1039/c1cc10143a",

language = "English",

volume = "47",

pages = "3380--3382",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks

AU - Burrows, Andrew D

AU - Fisher, Laura C

AU - Richardson, C

AU - Rigby, Sean P

PY - 2011/3/28

Y1 - 2011/3/28

N2 - Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn4O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.

AB - Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H(2)bdc) and 2-halo-1,4-benzenedicarboxylic acid (H(2)bdc-X, X = Br or I) to give [Zn4O(bdc)(3-x)(bdc-X)(x)], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.

UR - https://www.scopus.com/pages/publications/79952386395

UR - http://dx.doi.org/10.1039/c1cc10143a

U2 - 10.1039/c1cc10143a

DO - 10.1039/c1cc10143a

M3 - Article

SN - 1359-7345

VL - 47

SP - 3380

EP - 3382

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks

Abstract

Access to Document

Other files and links

Fingerprint

A NEW TYPE OF HETEROGENEOUS CATALYST FOR PROCESSES INVOLVING HYDROGENATIONS

Cite this

Selective incorporation of functional dicarboxylates into zinc metal-organic frameworks

Abstract

Access to Document

Other files and links

Fingerprint

Projects

A NEW TYPE OF HETEROGENEOUS CATALYST FOR PROCESSES INVOLVING HYDROGENATIONS

Cite this