[Sb12{(2-MeO)C6H4N} 18]̇6THF; A twenty-four membered imidoantimony(III) metallacycle

Michael A. Beswick, Maxwell K. Davies, Michael A. Paver, Paul R. Raithby, Alexander Steiner, Dominic S. Wright

Research output: Contribution to journalArticlepeer-review

21 Citations (SciVal)


Six Sb2N2 rings linked by single imido–N bridges to give a 24-membered ring characterize the structure of the title compound (the core is shown on the right). This is the largest Group 15 metal–imido complex to be structurally characterized and the first p block metal–imido metallacycle.
Original languageEnglish
Pages (from-to)1508-1510
Number of pages3
JournalAngewandte Chemie (International Edition in English)
Issue number13-14
Publication statusPublished - 31 Jul 1996


  • Antimony compounds
  • Complexes with nitrogen ligands
  • Imido complexes
  • Metallacycles

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry


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