[Sb12{(2-MeO)C6H4N} 18]̇6THF; A twenty-four membered imidoantimony(III) metallacycle

Michael A. Beswick, Maxwell K. Davies, Michael A. Paver, Paul R. Raithby, Alexander Steiner, Dominic S. Wright

Research output: Contribution to journalArticlepeer-review

Abstract

Six Sb2N2 rings linked by single imido–N bridges to give a 24-membered ring characterize the structure of the title compound (the core is shown on the right). This is the largest Group 15 metal–imido complex to be structurally characterized and the first p block metal–imido metallacycle.
Original languageEnglish
Pages (from-to)1508-1510
Number of pages3
JournalAngewandte Chemie (International Edition in English)
Volume35
Issue number13-14
DOIs
Publication statusPublished - 31 Jul 1996

Keywords

  • Antimony compounds
  • Complexes with nitrogen ligands
  • Imido complexes
  • Metallacycles

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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