[Sb12{(2-MeO)C6H4N} 18]̇6THF; A twenty-four membered imidoantimony(III) metallacycle

Michael A. Beswick; Maxwell K. Davies; Michael A. Paver; Paul R. Raithby; Alexander Steiner; Dominic S. Wright

doi:10.1002/anie.199615081

[Sb₁₂{(2-MeO)C₆H₄N} ₁₈]̇6THF; A twenty-four membered imidoantimony(III) metallacycle

Michael A. Beswick, Maxwell K. Davies, Michael A. Paver, Paul R. Raithby, Alexander Steiner, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

21 Citations (SciVal)

Abstract

Six Sb₂N₂ rings linked by single imido–N bridges to give a 24-membered ring characterize the structure of the title compound (the core is shown on the right). This is the largest Group 15 metal–imido complex to be structurally characterized and the first p block metal–imido metallacycle.

Original language	English
Pages (from-to)	1508-1510
Number of pages	3
Journal	Angewandte Chemie (International Edition in English)
Volume	35
Issue number	13-14
DOIs	https://doi.org/10.1002/anie.199615081
Publication status	Published - 31 Jul 1996

Keywords

Antimony compounds
Complexes with nitrogen ligands
Imido complexes
Metallacycles

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.199615081

Cite this

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abstract = "Six Sb2N2 rings linked by single imido–N bridges to give a 24-membered ring characterize the structure of the title compound (the core is shown on the right). This is the largest Group 15 metal–imido complex to be structurally characterized and the first p block metal–imido metallacycle.",

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AU - Beswick, Michael A.

AU - Davies, Maxwell K.

AU - Paver, Michael A.

AU - Raithby, Paul R.

AU - Steiner, Alexander

AU - Wright, Dominic S.

PY - 1996/7/31

Y1 - 1996/7/31

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AB - Six Sb2N2 rings linked by single imido–N bridges to give a 24-membered ring characterize the structure of the title compound (the core is shown on the right). This is the largest Group 15 metal–imido complex to be structurally characterized and the first p block metal–imido metallacycle.

KW - Antimony compounds

KW - Complexes with nitrogen ligands

KW - Imido complexes

KW - Metallacycles

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DO - 10.1002/anie.199615081

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AN - SCOPUS:0029783595

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