Ruthenium N-Heterocyclic Carbene Complexes for the Catalysis of Nonmetathesis Organic Transformations

Leonid Schwartsburd, Michael K. Whittlesey

Research output: Chapter in Book/Report/Conference proceedingChapter

7 Citations (Scopus)

Abstract

Ruthenium N-heterocyclic carbene (NHC) complexes have been at the forefront of the development of NHCs into the ubiquitous ligands now found in organometallic catalysis. This chapter reveals quite clearly not only a continued growth in interest in Ru-NHC catalysis, but more obviously, a very significant diversification of catalytic applications. The hydrogenation chemistry of half-sandwich Ru complexes containing primary amino functionalized NHC ligands has been developed principally by the Morris group. Some of the Ru-NHC catalysts active for transfer hydrogenation have also been used in the direct hydrogenation. There has been significant interest and significant developments in the use of Ru-NHC complexes for the so-called borrowing hydrogen reactions, which brings about temporary oxidation of alcohols to aldehydes and ketones, which are then utilized for the formation of new C-C and C-N bonds. Neutral half-sandwich complexes of the form [Cp*LRu(NHC)Cl] have been employed in the racemization of chiral alcohols.

Original languageEnglish
Title of host publicationN-Heterocyclic Carbenes
Subtitle of host publicationEffective Tools for Organometallic Synthesis
EditorsSteven P Nolan
PublisherWiley-Blackwell
Pages341-370
Number of pages30
ISBN (Electronic)9783527671229
ISBN (Print)9783527334902
DOIs
Publication statusPublished - 2014

Keywords

  • Alcohol Racemization
  • Borrowing hydrogen reactions
  • Direct hydrogenation
  • Organometallic catalysis
  • Ruthenium N-heterocyclic carbene (NHC) complexes
  • Transfer hydrogenation

ASJC Scopus subject areas

  • Chemistry(all)

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