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Abstract
The tandem isomerization and nucleophilic aromatic substitution of allylic fluoro-substituted benzylic alcohols is described for the first time. In the presence of the ruthenium complex Ru(PPh3)3(CO)(H) 2, 1-(4-fluorophenyl)prop-2-en-1-ol is converted into the corresponding para-amino ketone or para-phenolic substituted ketone.
Original language | English |
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Pages (from-to) | 734-740 |
Number of pages | 7 |
Journal | Advanced Synthesis & Catalysis |
Volume | 355 |
Issue number | 4 |
Early online date | 22 Feb 2013 |
DOIs | |
Publication status | Published - 11 Mar 2013 |
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Dive into the research topics of 'Ruthenium-catalyzed remote electronic activation of aromatic C-F bonds'. Together they form a unique fingerprint.Projects
- 1 Finished
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Dream Fellowship
Williams, J. (PI)
Engineering and Physical Sciences Research Council
1/08/11 → 10/05/13
Project: Research council