Ruthenium-catalyzed ortho-alkylation of phenols with alcohols by dehydrative coupling

J.W. Walton; Jonathan M J Williams

doi:10.1002/anie.201206246

Ruthenium-catalyzed ortho-alkylation of phenols with alcohols by dehydrative coupling

J.W. Walton, Jonathan M J Williams

Research output: Contribution to journal › Article › peer-review

26 Citations (SciVal)

Abstract

Only water: Phenols have been shown to undergo a ruthenium-catalyzed ortho-alkylation reaction (see scheme; Cy=cyclohexyl). Unactivated alcohols are used as the alkylating agents and water is the only by-product that is generated, making this transformation more atom-economical and greener than traditional methods.

Original language	English
Pages (from-to)	12166-12168
Number of pages	3
Journal	Angewandte Chemie International Edition
Volume	51
Issue number	49
DOIs	https://doi.org/10.1002/anie.201206246
Publication status	Published - 3 Dec 2012

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10.1002/anie.201206246

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title = "Ruthenium-catalyzed ortho-alkylation of phenols with alcohols by dehydrative coupling",

abstract = "Only water: Phenols have been shown to undergo a ruthenium-catalyzed ortho-alkylation reaction (see scheme; Cy=cyclohexyl). Unactivated alcohols are used as the alkylating agents and water is the only by-product that is generated, making this transformation more atom-economical and greener than traditional methods. ",

author = "J.W. Walton and Williams, \{Jonathan M J\}",

year = "2012",

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doi = "10.1002/anie.201206246",

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AU - Walton, J.W.

AU - Williams, Jonathan M J

PY - 2012/12/3

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N2 - Only water: Phenols have been shown to undergo a ruthenium-catalyzed ortho-alkylation reaction (see scheme; Cy=cyclohexyl). Unactivated alcohols are used as the alkylating agents and water is the only by-product that is generated, making this transformation more atom-economical and greener than traditional methods.

AB - Only water: Phenols have been shown to undergo a ruthenium-catalyzed ortho-alkylation reaction (see scheme; Cy=cyclohexyl). Unactivated alcohols are used as the alkylating agents and water is the only by-product that is generated, making this transformation more atom-economical and greener than traditional methods.

UR - https://www.scopus.com/pages/publications/84870514755

UR - http://dx.doi.org/10.1002/anie.201206246

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DO - 10.1002/anie.201206246

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SN - 1433-7851

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JO - Angewandte Chemie International Edition

JF - Angewandte Chemie International Edition

IS - 49

ER -

Ruthenium-catalyzed ortho-alkylation of phenols with alcohols by dehydrative coupling

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Ruthenium-catalyzed ortho-alkylation of phenols with alcohols by dehydrative coupling

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