[Ru20H4Cu6Cl2(CO) 48]4-: A New High Nuclearity Copper-Ruthenium Cluster

Michael A. Beswick; Jack Lewis; Paul R. Raithby; M. Carmen Ramirez De Arellano

doi:10.1002/anie.199722271

[Ru₂₀H₄Cu₆Cl₂(CO) ₄₈]^4-: A New High Nuclearity Copper-Ruthenium Cluster

Michael A. Beswick, Jack Lewis, Paul R. Raithby, M. Carmen Ramirez De Arellano

University of Cambridge

Research output: Contribution to journal › Article › peer-review

26 Citations (SciVal)

Abstract

A precursor for Cu/Ru mixed-metal catalysts? This is one of the potential applications of the title cluster (structure of the Ru20Cu6Cl2 framework shown below), which can be isolated as the nBu4N+ salt from the reaction of [(Ph3P)2N]2[Ru10H2(CO)25] with nBu4NOH/H2O,[Cu(MeCN)4], and (Ph3P)2NCl.

Original language	English
Pages (from-to)	2227-2228
Number of pages	2
Journal	Angewandte Chemie (International Edition in English)
Volume	36
Issue number	20
DOIs	https://doi.org/10.1002/anie.199722271
Publication status	Published - 3 Nov 1997

Keywords

Carbonyl complexes
Clusters
Copper
Ruthenium
Structure elucidation

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.199722271

Cite this

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abstract = "A precursor for Cu/Ru mixed-metal catalysts? This is one of the potential applications of the title cluster (structure of the Ru20Cu6Cl2 framework shown below), which can be isolated as the nBu4N+ salt from the reaction of [(Ph3P)2N]2[Ru10H2(CO)25] with nBu4NOH/H2O,[Cu(MeCN)4], and (Ph3P)2NCl.",

keywords = "Carbonyl complexes, Clusters, Copper, Ruthenium, Structure elucidation",

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AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Ramirez De Arellano, M. Carmen

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AB - A precursor for Cu/Ru mixed-metal catalysts? This is one of the potential applications of the title cluster (structure of the Ru20Cu6Cl2 framework shown below), which can be isolated as the nBu4N+ salt from the reaction of [(Ph3P)2N]2[Ru10H2(CO)25] with nBu4NOH/H2O,[Cu(MeCN)4], and (Ph3P)2NCl.

KW - Carbonyl complexes

KW - Clusters

KW - Copper

KW - Ruthenium

KW - Structure elucidation

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