Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes

Ruth Webster

Research output: Contribution to journal › Article

Abstract

The catalytic activity of nickel complexes in hydrophosphination involving secondary phosphines is not a commonly studied transformation. Beyond a small number of stand-out examples, many reports in the literature focus on the use of simple nickel salts. β-Diketiminates have been proven to be incredibly effective ligands for catalysis using a range of metal centers. This synthetic study investigates the catalytic ability of a Ni(II) β-diketiminate complex in the hydrophosphination of alkenes and alkynes, with a serendipitous discovery of its ability to effect alkyne cyclotrimerization and phosphine dehydrocoupling
LanguageEnglish
Article number120
JournalInorganics
Volume6
Issue number4
Early online date2 Nov 2018
DOIs
StatusPublished - 1 Dec 2018

Keywords

  • Alkenes
  • Alkynes
  • Catalysis
  • Hydrophosphination
  • Nickel
  • Phosphines
  • β-diketiminates

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes. / Webster, Ruth.

In: Inorganics, Vol. 6, No. 4, 120, 01.12.2018.

Research output: Contribution to journal › Article

Webster, R 2018, 'Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes', Inorganics, vol. 6, no. 4, 120. https://doi.org/10.3390/inorganics6040120
Webster R. Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes. Inorganics. 2018 Dec 1;6(4). 120. https://doi.org/10.3390/inorganics6040120
Webster, Ruth. / Room Temperature Ni(II) Catalyzed Hydrophosphination and Cyclotrimerization of Alkynes. In: Inorganics. 2018 ; Vol. 6, No. 4.
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