Roles of oxygen vacancies in layered double hydroxides-based catalysts for wastewater remediation: fundamentals and prospects

Wastewater globally is a significant concern for environmental health and for the sustainable management of water resources. Catalysed based advanced oxidation processes (AOP), as a relatively low operation cost and high removal efficiency of pollutants method, has a promising potential to treat the wastewater. Among the numerous catalysts, Layered Double Hydroxides (LDHs) stands out for lamellar structure, high charge density, and tuneable properties. Meanwhile, oxygen vacancies engineering could modulate the electronic properties of materials and create active centres to regulate the poor charge transfer capability of LDHs. In this regard, this review is focused on how to create and confirm the oxygen vacancies, as well as the applications of the wastewater treatment from different AOPs. It starts with the synthesized of oxygen vacancies via chemical reduction method, plasma etching method, hydrothermal treatment method, ion doping strategy. Followed by the description of characterization methods, including EPR, XPS, XAS, Raman. Finally, the role of oxygen vacancies in LDHs for contaminant removal across various systems, including photocatalysis, electrocatalysis, Fenton reactions, and sulfate radical-based processes, was thoroughly examined and analyzed.