Role of Cobalt−Iron (Oxy)Hydroxide (CoFeOx) as Oxygen Evolution Catalyst on Hematite Photoanodes

Jifang Zhang, Rodrigo García-Rodríguez, Petra Cameron, Salvador Eslava

Research output: Contribution to journalArticlepeer-review

119 Citations (SciVal)


Photoelectrochemical solar water splitting into hydrogen and oxygen offers an elegant and potentially efficient way to store solar energy in the chemical bonds of hydrogen, but the oxygen evolution rate is quite limited. The deposition of an oxygen evolution catalyst on the photoanode can enhance oxygen evolution, although the precise interplay between the semiconductor and the catalyst remains poorly understood and unoptimized. In this work, we use a combination of electrochemical approaches, including photoelectrochemical impedance spectroscopy and intensity modulated photocurrent spectroscopy, to unravel the nature of the interactions between different loadings of an electrocatalyst (CoFeOx) and a hematite (α-Fe2O3) semiconductor. A thin layer of CoFeOx mainly reduces surface charge recombination, while an extremely thin layer enhances charge transfer kinetics. Moreover, an interlayer of GaOx modifies the surface state distribution and increases the charge transfer rate even further. These findings point to new opportunities for understanding and manipulating complex photoanodes for oxygen evolution.
Original languageEnglish
Pages (from-to)2972-2984
Number of pages13
JournalEnergy & Environmental Science
Early online date18 Jul 2018
Publication statusE-pub ahead of print - 18 Jul 2018

ASJC Scopus subject areas

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution


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