Ring expansion of a ring expanded carbene

Lucia Garcia Rodriguez; Khalidah Al Fahraiji; David J. D. Wilson; Jason Dutton; Michael Hill; Mary Mahon

doi:10.1039/c7dt03046k

Ring expansion of a ring expanded carbene

Lucia Garcia Rodriguez, Khalidah Al Fahraiji, David J. D. Wilson, Jason Dutton, Michael Hill, Mary Mahon

La Trobe University

Research output: Contribution to journal › Article › peer-review

13 Citations (SciVal)

Abstract

Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.

Original language	English
Pages (from-to)	12015-12018
Number of pages	4
Journal	Dalton Transactions
Volume	46
Issue number	36
Early online date	21 Aug 2017
DOIs	https://doi.org/10.1039/c7dt03046k
Publication status	Published - 28 Sept 2017

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10.1039/c7dt03046kLicence: CC BY

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title = "Ring expansion of a ring expanded carbene",

abstract = "Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.",

author = "{Garcia Rodriguez}, Lucia and {Al Fahraiji}, Khalidah and Wilson, {David J. D.} and Jason Dutton and Michael Hill and Mary Mahon",

year = "2017",

month = sep,

day = "28",

doi = "10.1039/c7dt03046k",

language = "English",

volume = "46",

pages = "12015--12018",

journal = "Dalton Transactions ",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "36",

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TY - JOUR

T1 - Ring expansion of a ring expanded carbene

AU - Garcia Rodriguez, Lucia

AU - Al Fahraiji, Khalidah

AU - Wilson, David J. D.

AU - Dutton, Jason

AU - Hill, Michael

AU - Mahon, Mary

PY - 2017/9/28

Y1 - 2017/9/28

N2 - Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.

AB - Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.

UR - http://doi.org/10.1039/C7DT03046K

UR - http://dx.doi/10.1039/C7DT03046K

U2 - 10.1039/c7dt03046k

DO - 10.1039/c7dt03046k

M3 - Article

SN - 1477-9226

VL - 46

SP - 12015

EP - 12018

JO - Dalton Transactions

JF - Dalton Transactions

IS - 36

ER -

Ring expansion of a ring expanded carbene

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Augmentation of Alkaline Earth Reactivity: An FLP Analogy

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Ring expansion of a ring expanded carbene

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Augmentation of Alkaline Earth Reactivity: An FLP Analogy

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