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Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.
FingerprintDive into the research topics of 'Ring expansion of a ring expanded carbene'. Together they form a unique fingerprint.
- 1 Finished
8/02/16 → 6/02/20
Project: Research council