Ring expansion of a ring expanded carbene

Lucia Garcia Rodriguez, Khalidah Al Fahraiji, David J. D. Wilson, Jason Dutton, Michael Hill, Mary Mahon

Research output: Contribution to journalArticle

Abstract

Reaction of phenylsilane with the ring expanded carbene 6-Mes results in facile Si-H oxidative addition to the carbenic carbon at room temperature. Heating the resultant diorganosilane product induces ring expansion through silicon to carbon migration of either the Si-H or Si-Ph bonds.
LanguageEnglish
Pages12015-12018
Number of pages4
JournalDalton Transactions
Volume46
Issue number36
Early online date21 Aug 2017
DOIs
StatusPublished - 28 Sep 2017

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Carbon
Silicon
Heating
Temperature
carbene

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Ring expansion of a ring expanded carbene. / Garcia Rodriguez, Lucia; Al Fahraiji, Khalidah; Wilson, David J. D.; Dutton, Jason; Hill, Michael; Mahon, Mary.

In: Dalton Transactions , Vol. 46, No. 36, 28.09.2017, p. 12015-12018.

Research output: Contribution to journalArticle

Garcia Rodriguez, L, Al Fahraiji, K, Wilson, DJD, Dutton, J, Hill, M & Mahon, M 2017, 'Ring expansion of a ring expanded carbene' Dalton Transactions , vol. 46, no. 36, pp. 12015-12018. DOI: 10.1039/c7dt03046k
Garcia Rodriguez L, Al Fahraiji K, Wilson DJD, Dutton J, Hill M, Mahon M. Ring expansion of a ring expanded carbene. Dalton Transactions . 2017 Sep 28;46(36):12015-12018. Available from, DOI: 10.1039/c7dt03046k
Garcia Rodriguez, Lucia ; Al Fahraiji, Khalidah ; Wilson, David J. D. ; Dutton, Jason ; Hill, Michael ; Mahon, Mary. / Ring expansion of a ring expanded carbene. In: Dalton Transactions . 2017 ; Vol. 46, No. 36. pp. 12015-12018
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