Rhodium containing magnetic nanoparticles: effective catalysts for hydrogenation and the 1,4-addition of boronic acids

Urszula Laska; Christopher G Frost; Pawel K Plucinski; Gareth J Price

doi:10.1007/s10562-007-9339-7

Rhodium containing magnetic nanoparticles: effective catalysts for hydrogenation and the 1,4-addition of boronic acids

Urszula Laska, Christopher G Frost, Pawel K Plucinski, Gareth J Price

Research output: Contribution to journal › Article › peer-review

33 Citations (SciVal)

Abstract

New efficient rhodium catalysts supported on superparamagnetic iron oxide nanoparticles (NPs) have been prepd. using a novel method involving sulfonated triphenylphosphine ligands. They successfully promote the hydrogenation of olefins as well as the addn. of arylboronic acids to di-Me itaconate in water for up to 10 recycles. The catalysts were stable towards leaching of the metal complexes and were readily recovered by applying an external magnetic field.

Original language	English
Pages (from-to)	68-75
Number of pages	8
Journal	Catalysis Letters
Volume	122
Issue number	1-2
Early online date	1 Dec 2007
DOIs	https://doi.org/10.1007/s10562-007-9339-7
Publication status	Published - 1 Apr 2008

Keywords

Addition reaction
Addition reaction catalysts (conjugate
magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1
Nanoparticles (magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1
Alkenes
Hydrogenation
RACT (Reactant or reagent) (magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1
hydrogenation alkene rhodium catalyst iron oxide nanoparticle supported
RCT (Reactant)
rhodium catalyst iron oxide nanoparticle supported hydrogenation addn
4-addn. of boronic acids)
Hydrogenation catalysts
arylboronic addn itaconate rhodium catalyst iron oxide nanoparticle supported
Boronic acids Role

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10.1007/s10562-007-9339-7

Cite this

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title = "Rhodium containing magnetic nanoparticles: effective catalysts for hydrogenation and the 1,4-addition of boronic acids",

abstract = "New efficient rhodium catalysts supported on superparamagnetic iron oxide nanoparticles (NPs) have been prepd. using a novel method involving sulfonated triphenylphosphine ligands. They successfully promote the hydrogenation of olefins as well as the addn. of arylboronic acids to di-Me itaconate in water for up to 10 recycles. The catalysts were stable towards leaching of the metal complexes and were readily recovered by applying an external magnetic field. ",

keywords = "Addition reaction, Addition reaction catalysts (conjugate, magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1, Nanoparticles (magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1, Alkenes, Hydrogenation, RACT (Reactant or reagent) (magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1, hydrogenation alkene rhodium catalyst iron oxide nanoparticle supported, RCT (Reactant), rhodium catalyst iron oxide nanoparticle supported hydrogenation addn, 4-addn. of boronic acids), Hydrogenation catalysts, arylboronic addn itaconate rhodium catalyst iron oxide nanoparticle supported, Boronic acids Role",

author = "Urszula Laska and Frost, {Christopher G} and Plucinski, {Pawel K} and Price, {Gareth J}",

year = "2008",

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doi = "10.1007/s10562-007-9339-7",

language = "English",

volume = "122",

pages = "68--75",

journal = "Catalysis Letters",

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number = "1-2",

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T1 - Rhodium containing magnetic nanoparticles: effective catalysts for hydrogenation and the 1,4-addition of boronic acids

AU - Laska, Urszula

AU - Frost, Christopher G

AU - Plucinski, Pawel K

AU - Price, Gareth J

PY - 2008/4/1

Y1 - 2008/4/1

N2 - New efficient rhodium catalysts supported on superparamagnetic iron oxide nanoparticles (NPs) have been prepd. using a novel method involving sulfonated triphenylphosphine ligands. They successfully promote the hydrogenation of olefins as well as the addn. of arylboronic acids to di-Me itaconate in water for up to 10 recycles. The catalysts were stable towards leaching of the metal complexes and were readily recovered by applying an external magnetic field.

AB - New efficient rhodium catalysts supported on superparamagnetic iron oxide nanoparticles (NPs) have been prepd. using a novel method involving sulfonated triphenylphosphine ligands. They successfully promote the hydrogenation of olefins as well as the addn. of arylboronic acids to di-Me itaconate in water for up to 10 recycles. The catalysts were stable towards leaching of the metal complexes and were readily recovered by applying an external magnetic field.

KW - Addition reaction

KW - Addition reaction catalysts (conjugate

KW - magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1

KW - Nanoparticles (magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1

KW - Alkenes

KW - Hydrogenation

KW - RACT (Reactant or reagent) (magnetic nanoparticle-immobilized rhodium complexes as effective catalysts for hydrogenation of olefins and the 1

KW - hydrogenation alkene rhodium catalyst iron oxide nanoparticle supported

KW - RCT (Reactant)

KW - rhodium catalyst iron oxide nanoparticle supported hydrogenation addn

KW - 4-addn. of boronic acids)

KW - Hydrogenation catalysts

KW - arylboronic addn itaconate rhodium catalyst iron oxide nanoparticle supported

KW - Boronic acids Role

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UR - http://dx.doi.org/10.1007/s10562-007-9339-7

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DO - 10.1007/s10562-007-9339-7

M3 - Article

SN - 1011-372X

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SP - 68

EP - 75

JO - Catalysis Letters

JF - Catalysis Letters

IS - 1-2

ER -

Rhodium containing magnetic nanoparticles: effective catalysts for hydrogenation and the 1,4-addition of boronic acids

Abstract

Keywords

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ENGINEERING FUNCTIONAL MATERIALS FOR CATALYTIC SMART MICRORE ACTORS

DISCIPLINE HOPPING - CATALYTIC ORGANIC SYNTHESIS IN SUB-, NE AR-, AND SUPER-CRITICAL WATER

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Rhodium containing magnetic nanoparticles: effective catalysts for hydrogenation and the 1,4-addition of boronic acids

Abstract

Keywords

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Projects

ENGINEERING FUNCTIONAL MATERIALS FOR CATALYTIC SMART MICRORE ACTORS

DISCIPLINE HOPPING - CATALYTIC ORGANIC SYNTHESIS IN SUB-, NE AR-, AND SUPER-CRITICAL WATER

Cite this