Rhodium catalysed tandem conjugate addition-protonation: An enantioselective synthesis of 2-substituted succinic esters

R. J. Moss; K. J. Wadsworth; C.J. Chapman; C.G. Frost

doi:10.1039/b406905f

Rhodium catalysed tandem conjugate addition-protonation: An enantioselective synthesis of 2-substituted succinic esters

R. J. Moss, K. J. Wadsworth, C.J. Chapman, C.G. Frost

Research output: Contribution to journal › Article › peer-review

59 Citations (SciVal)

Abstract

The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.

Original language	English
Pages (from-to)	1984-1985
Number of pages	2
Journal	Chemical Communications
Volume	10
Issue number	17
DOIs	https://doi.org/10.1039/b406905f
Publication status	Published - 7 Sept 2004

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title = "Rhodium catalysed tandem conjugate addition-protonation: An enantioselective synthesis of 2-substituted succinic esters",

abstract = "The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.",

author = "Moss, \{R. J.\} and Wadsworth, \{K. J.\} and C.J. Chapman and C.G. Frost",

year = "2004",

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journal = "Chemical Communications",

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T1 - Rhodium catalysed tandem conjugate addition-protonation

T2 - An enantioselective synthesis of 2-substituted succinic esters

AU - Moss, R. J.

AU - Wadsworth, K. J.

AU - Chapman, C.J.

AU - Frost, C.G.

PY - 2004/9/7

Y1 - 2004/9/7

N2 - The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.

AB - The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.

UR - https://www.scopus.com/pages/publications/5044232333

UR - http://dx.doi.org/10.1039/b406905f

U2 - 10.1039/b406905f

DO - 10.1039/b406905f

M3 - Article

AN - SCOPUS:5044232333

SN - 1359-7345

VL - 10

SP - 1984

EP - 1985

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Rhodium catalysed tandem conjugate addition-protonation: An enantioselective synthesis of 2-substituted succinic esters

Abstract

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