Rhodium catalysed tandem conjugate addition-protonation

An enantioselective synthesis of 2-substituted succinic esters

R. J. Moss, K. J. Wadsworth, C.J. Chapman, C.G. Frost

Research output: Contribution to journalArticle

49 Citations (Scopus)

Abstract

The rhodium catalysed addition of potassium trifluoro(organo)borates to dimethyl itaconate generates an intermediate complex which on protonation provides enantioenriched succinic esters.
Original languageEnglish
Pages (from-to)1984-1985
Number of pages2
JournalChemical Communications
Volume10
Issue number17
DOIs
Publication statusPublished - 7 Sep 2004

Fingerprint

Rhodium
Borates
Protonation
Succinic Acid
Potassium
Esters
dimethyl itaconate

Cite this

Rhodium catalysed tandem conjugate addition-protonation : An enantioselective synthesis of 2-substituted succinic esters. / Moss, R. J.; Wadsworth, K. J.; Chapman, C.J.; Frost, C.G.

In: Chemical Communications, Vol. 10, No. 17, 07.09.2004, p. 1984-1985.

Research output: Contribution to journalArticle

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