Rhodium catalysed conjugate addition of a chiral alkenyltrifluoroborate salt: The enantioselective synthesis of hermitamides A and B

Christopher Frost; Stephen Penrose; Robert Gleave

doi:10.1039/b812897a

Rhodium catalysed conjugate addition of a chiral alkenyltrifluoroborate salt: The enantioselective synthesis of hermitamides A and B

Christopher Frost, Stephen Penrose, Robert Gleave

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (SciVal)

Abstract

The concise enantioselective synthesis of hermitamides A and B is presented utilising a rhodium catalysed conjugate addition reaction to introduce the side chain and chiral information in a single step via an alkenyltrifluoroborate salt.

Original language	English
Pages (from-to)	4340-4347
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	6
Issue number	23
DOIs	https://doi.org/10.1039/b812897a
Publication status	Published - 2008

Keywords

Addition reactions
Rhodium
Chemical reactions
Aromatic hydrocarbons

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10.1039/b812897a

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title = "Rhodium catalysed conjugate addition of a chiral alkenyltrifluoroborate salt: The enantioselective synthesis of hermitamides A and B",

abstract = "The concise enantioselective synthesis of hermitamides A and B is presented utilising a rhodium catalysed conjugate addition reaction to introduce the side chain and chiral information in a single step via an alkenyltrifluoroborate salt.",

keywords = "Addition reactions, Rhodium, Chemical reactions, Aromatic hydrocarbons",

author = "Christopher Frost and Stephen Penrose and Robert Gleave",

year = "2008",

doi = "10.1039/b812897a",

language = "English",

volume = "6",

pages = "4340--4347",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "23",

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T1 - Rhodium catalysed conjugate addition of a chiral alkenyltrifluoroborate salt: The enantioselective synthesis of hermitamides A and B

AU - Frost, Christopher

AU - Penrose, Stephen

AU - Gleave, Robert

PY - 2008

Y1 - 2008

N2 - The concise enantioselective synthesis of hermitamides A and B is presented utilising a rhodium catalysed conjugate addition reaction to introduce the side chain and chiral information in a single step via an alkenyltrifluoroborate salt.

AB - The concise enantioselective synthesis of hermitamides A and B is presented utilising a rhodium catalysed conjugate addition reaction to introduce the side chain and chiral information in a single step via an alkenyltrifluoroborate salt.

KW - Addition reactions

KW - Rhodium

KW - Chemical reactions

KW - Aromatic hydrocarbons

UR - http://www.scopus.com/inward/record.url?scp=56349166151&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1039/b812897a

U2 - 10.1039/b812897a

DO - 10.1039/b812897a

M3 - Article

SN - 1477-0520

VL - 6

SP - 4340

EP - 4347

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 23

ER -

Rhodium catalysed conjugate addition of a chiral alkenyltrifluoroborate salt: The enantioselective synthesis of hermitamides A and B

Abstract

Keywords

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