Rhodium-catalysed 1,4-addition-halogenation: the crucial role of lithium halide

J.L. Nôtre; C.G. Frost

doi:10.1016/j.tetlet.2008.08.047

Rhodium-catalysed 1,4-addition-halogenation: the crucial role of lithium halide

J.L. Nôtre
, C.G. Frost

Research output: Contribution to journal › Article › peer-review

3 Citations (SciVal)

Abstract

The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts.

Original language	English
Pages (from-to)	6217-6219
Number of pages	3
Journal	Tetrahedron Letters
Volume	49
Issue number	43
DOIs	https://doi.org/10.1016/j.tetlet.2008.08.047
Publication status	Published - 20 Oct 2008

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title = "Rhodium-catalysed 1,4-addition-halogenation: the crucial role of lithium halide",

abstract = "The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts. ",

author = "J.L. N{\^o}tre and C.G. Frost",

year = "2008",

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doi = "10.1016/j.tetlet.2008.08.047",

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T2 - the crucial role of lithium halide

AU - Nôtre, J.L.

AU - Frost, C.G.

PY - 2008/10/20

Y1 - 2008/10/20

N2 - The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts.

AB - The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts.

UR - https://www.scopus.com/pages/publications/50949107485

UR - http://dx.doi.org/10.1016/j.tetlet.2008.08.047

U2 - 10.1016/j.tetlet.2008.08.047

DO - 10.1016/j.tetlet.2008.08.047

M3 - Article

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SN - 0040-4039

VL - 49

SP - 6217

EP - 6219

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 43

ER -

Rhodium-catalysed 1,4-addition-halogenation: the crucial role of lithium halide

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