Rhodium-catalysed 1,4-addition-halogenation

the crucial role of lithium halide

J.L. Nôtre, C.G. Frost

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts.
Original languageEnglish
Pages (from-to)6217-6219
Number of pages3
JournalTetrahedron Letters
Volume49
Issue number43
DOIs
Publication statusPublished - 20 Oct 2008

Fingerprint

Halogenation
Rhodium
Lithium
Salts
dimethyl itaconate

Cite this

Rhodium-catalysed 1,4-addition-halogenation : the crucial role of lithium halide. / Nôtre, J.L.; Frost, C.G.

In: Tetrahedron Letters, Vol. 49, No. 43, 20.10.2008, p. 6217-6219.

Research output: Contribution to journalArticle

@article{3d64d9406d6c4fe495a533a362aee5ae,
title = "Rhodium-catalysed 1,4-addition-halogenation: the crucial role of lithium halide",
abstract = "The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts.",
author = "J.L. N{\^o}tre and C.G. Frost",
year = "2008",
month = "10",
day = "20",
doi = "10.1016/j.tetlet.2008.08.047",
language = "English",
volume = "49",
pages = "6217--6219",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier",
number = "43",

}

TY - JOUR

T1 - Rhodium-catalysed 1,4-addition-halogenation

T2 - the crucial role of lithium halide

AU - Nôtre, J.L.

AU - Frost, C.G.

PY - 2008/10/20

Y1 - 2008/10/20

N2 - The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts.

AB - The rhodium-catalysed 1,4-addition-iodination or 1,4-addition-bromination of dimethylitaconate has been accomplished in high yield using arylzinc reagents and electrophilic halogenating agents. The product distribution is influenced by the presence of specific lithium halide salts.

UR - http://www.scopus.com/inward/record.url?scp=50949107485&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1016/j.tetlet.2008.08.047

U2 - 10.1016/j.tetlet.2008.08.047

DO - 10.1016/j.tetlet.2008.08.047

M3 - Article

VL - 49

SP - 6217

EP - 6219

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 43

ER -