Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

A Thapper; E Sparr; B F G Johnson; J Lewis; P R Raithby; E Nordlander

doi:10.1016/j.inoche.2003.12.032

Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

A Thapper
, E Sparr
, B F G Johnson
, J Lewis
, P R Raithby
, E Nordlander

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (SciVal)

Abstract

The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	443-446
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2003.12.032
Publication status	Published - 2004

Bibliographical note

ID number: ISI:000189229800037

Access to Document

10.1016/j.inoche.2003.12.032

Cite this

@article{a12f92ce20d94ad3837426bcd3387840,

title = "Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster",

abstract = "The triallylphosphine-substituted clusters [Ru-3(CO)(10)\{P(CH2CH=CH2)(3)\}], [Ru-3(CO)(10)\{P(CH2CH=CH2)(3)\}(2)] and [Ru-3(CO)(10) \{sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)\}] have been prepared; reaction of [Ru-3(CO)(10)\{sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)\}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11)\{P(CH2CH=CH2)(3)\}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.",

author = "A Thapper and E Sparr and Johnson, \{B F G\} and J Lewis and Raithby, \{P R\} and E Nordlander",

note = "ID number: ISI:000189229800037",

year = "2004",

doi = "10.1016/j.inoche.2003.12.032",

language = "English",

volume = "7",

pages = "443--446",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

AU - Thapper, A

AU - Sparr, E

AU - Johnson, B F G

AU - Lewis, J

AU - Raithby, P R

AU - Nordlander, E

N1 - ID number: ISI:000189229800037

PY - 2004

Y1 - 2004

N2 - The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.

AB - The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.inoche.2003.12.032

DO - 10.1016/j.inoche.2003.12.032

M3 - Article

SN - 1387-7003

VL - 7

SP - 443

EP - 446

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

ER -

Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

Abstract

Bibliographical note

Access to Document

Fingerprint

Cite this