Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

A Thapper, E Sparr, B F G Johnson, J Lewis, P R Raithby, E Nordlander

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Abstract

The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)443-446
Number of pages4
JournalInorganic Chemistry Communications
Volume7
Issue number3
DOIs
Publication statusPublished - 2004

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Ruthenium
Carbon Monoxide
phosphines
ruthenium
cleavage
Phosphines
Phosphites

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Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster. / Thapper, A; Sparr, E; Johnson, B F G; Lewis, J; Raithby, P R; Nordlander, E.

In: Inorganic Chemistry Communications, Vol. 7, No. 3, 2004, p. 443-446.

Research output: Contribution to journalArticle

Thapper, A ; Sparr, E ; Johnson, B F G ; Lewis, J ; Raithby, P R ; Nordlander, E. / Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster. In: Inorganic Chemistry Communications. 2004 ; Vol. 7, No. 3. pp. 443-446.
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abstract = "The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.",
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T1 - Reversible pi-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

AU - Thapper, A

AU - Sparr, E

AU - Johnson, B F G

AU - Lewis, J

AU - Raithby, P R

AU - Nordlander, E

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N2 - The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.

AB - The triallylphosphine-substituted clusters [Ru-3(CO)(10){P(CH2CH=CH2)(3)}], [Ru-3(CO)(10){P(CH2CH=CH2)(3)}(2)] and [Ru-3(CO)(10) {sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] have been prepared; reaction of [Ru-3(CO)(10){sigma;pi-CH2=CHCH2P(CH2CH=CH2)(2)}] with phosphines/phosphites leads to cleavage of the Ru-allyl pi-bond and formation of [Ru-3(CO)(11){P(CH2CH=CH2)(3)}(PR3)]. (C) 2004 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.inoche.2003.12.032

DO - 10.1016/j.inoche.2003.12.032

M3 - Article

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