Reversible oxidation of [MonW3-n(η5-C5H 5)3(CO)6(μ3-P)] (n = 0-3) by sulfur; synthesis and characterisation of [MonW3-n(η5-C5H 5)3(CO)6(μ3-PS)] (n = 0-3)

John E. Davies; Martin J. Mays; Elizabeth J. Pook; Paul R. Raithby; Peter K. Tompkin

Reversible oxidation of [Mo_nW_3-n(η⁵-C₅H ₅)₃(CO)₆(μ₃-P)] (n = 0-3) by sulfur; synthesis and characterisation of [Mo_nW_3-n(η⁵-C₅H ₅)₃(CO)₆(μ₃-PS)] (n = 0-3)

John E. Davies, Martin J. Mays, Elizabeth J. Pook, Paul R. Raithby, Peter K. Tompkin

University of Cambridge

Research output: Contribution to journal › Article › peer-review

19 Citations (SciVal)

Abstract

The trimetallic tetrahedrane complexes [Mo_nW_3-n(η⁵-C₅H ₅)₃(CO)₆(μ₃-P)] (n = 0-3) are oxidised in carbon disulfide solution by elemental sulfur to the corresponding μ₃-PS complexes [Mo_nW_3-n(η⁵-C₅H ₅)₃(CO)₆(μ₃-PS)]; the new complexes lose the sulfur atom upon standing in solution at room temp, to regenerate [Mo_nW_3-n(η⁵-C₅H ₅)(CO)₆(μ₃-P)]; the X-ray crystal structure of [W₃(η⁵-C₅H₅) ₃(CO)₆(μ₃-PS)] is determined.

Original language	English
Pages (from-to)	1997-1998
Number of pages	2
Journal	Chemical Communications
Issue number	20
Publication status	Published - 1 Jan 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

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title = "Reversible oxidation of [MonW3-n(η5-C5H 5)3(CO)6(μ3-P)] (n = 0-3) by sulfur; synthesis and characterisation of [MonW3-n(η5-C5H 5)3(CO)6(μ3-PS)] (n = 0-3)",

abstract = "The trimetallic tetrahedrane complexes [MonW3-n(η5-C5H 5)3(CO)6(μ3-P)] (n = 0-3) are oxidised in carbon disulfide solution by elemental sulfur to the corresponding μ3-PS complexes [MonW3-n(η5-C5H 5)3(CO)6(μ3-PS)]; the new complexes lose the sulfur atom upon standing in solution at room temp, to regenerate [MonW3-n(η5-C5H 5)(CO)6(μ3-P)]; the X-ray crystal structure of [W3(η5-C5H5) 3(CO)6(μ3-PS)] is determined.",

author = "Davies, {John E.} and Mays, {Martin J.} and Pook, {Elizabeth J.} and Raithby, {Paul R.} and Tompkin, {Peter K.}",

year = "1997",

month = jan,

day = "1",

language = "English",

pages = "1997--1998",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "20",

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TY - JOUR

T1 - Reversible oxidation of [MonW3-n(η5-C5H 5)3(CO)6(μ3-P)] (n = 0-3) by sulfur; synthesis and characterisation of [MonW3-n(η5-C5H 5)3(CO)6(μ3-PS)] (n = 0-3)

AU - Davies, John E.

AU - Mays, Martin J.

AU - Pook, Elizabeth J.

AU - Raithby, Paul R.

AU - Tompkin, Peter K.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The trimetallic tetrahedrane complexes [MonW3-n(η5-C5H 5)3(CO)6(μ3-P)] (n = 0-3) are oxidised in carbon disulfide solution by elemental sulfur to the corresponding μ3-PS complexes [MonW3-n(η5-C5H 5)3(CO)6(μ3-PS)]; the new complexes lose the sulfur atom upon standing in solution at room temp, to regenerate [MonW3-n(η5-C5H 5)(CO)6(μ3-P)]; the X-ray crystal structure of [W3(η5-C5H5) 3(CO)6(μ3-PS)] is determined.

AB - The trimetallic tetrahedrane complexes [MonW3-n(η5-C5H 5)3(CO)6(μ3-P)] (n = 0-3) are oxidised in carbon disulfide solution by elemental sulfur to the corresponding μ3-PS complexes [MonW3-n(η5-C5H 5)3(CO)6(μ3-PS)]; the new complexes lose the sulfur atom upon standing in solution at room temp, to regenerate [MonW3-n(η5-C5H 5)(CO)6(μ3-P)]; the X-ray crystal structure of [W3(η5-C5H5) 3(CO)6(μ3-PS)] is determined.

UR - http://www.scopus.com/inward/record.url?scp=1542474648&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:1542474648

SN - 1359-7345

SP - 1997

EP - 1998

JO - Chemical Communications

JF - Chemical Communications

IS - 20

ER -

Reversible oxidation of [Mo_nW_3-n(η⁵-C₅H ₅)₃(CO)₆(μ₃-P)] (n = 0-3) by sulfur; synthesis and characterisation of [Mo_nW_3-n(η⁵-C₅H ₅)₃(CO)₆(μ₃-PS)] (n = 0-3)

Abstract

ASJC Scopus subject areas

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