Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

T M Douglas, S K Brayshaw, P R Raithby, A S Weller

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.
Original languageEnglish
Pages (from-to)778-780
Number of pages3
JournalInorganic Chemistry
Volume47
Issue number3
DOIs
Publication statusPublished - 2008

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