Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

T M Douglas; S K Brayshaw; P R Raithby; A S Weller

doi:10.1021/ic702195b

Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

T M Douglas, S K Brayshaw, P R Raithby, A S Weller

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (SciVal)

Abstract

The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.

Original language	English
Pages (from-to)	778-780
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	3
DOIs	https://doi.org/10.1021/ic702195b
Publication status	Published - 2008

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ID number: ISI:000252714500007

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title = "Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)",

abstract = "The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.",

author = "Douglas, {T M} and Brayshaw, {S K} and Raithby, {P R} and Weller, {A S}",

note = "ID number: ISI:000252714500007",

year = "2008",

doi = "10.1021/ic702195b",

language = "English",

volume = "47",

pages = "778--780",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "3",

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TY - JOUR

T1 - Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

AU - Douglas, T M

AU - Brayshaw, S K

AU - Raithby, P R

AU - Weller, A S

N1 - ID number: ISI:000252714500007

PY - 2008

Y1 - 2008

N2 - The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.

AB - The hydroxyhydrido salt [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2) results from the addition of water to [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). This reaction is ;reversible, and the addition of dihydrogen to [Rh-6((PPr3)-Pr-i)(6)H-11(OH)]- [BAr4F](2) results in the elimination of water and the regeneration of the hydride cluster.

UR - http://www.scopus.com/inward/record.url?scp=39749124288&partnerID=8YFLogxK

U2 - 10.1021/ic702195b

DO - 10.1021/ic702195b

M3 - Article

SN - 0020-1669

VL - 47

SP - 778

EP - 780

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Reversible addition of water to the high-hydride-content cluster [Rh-6((PPr3)-Pr-i)(6)H-12][BAr4F](2). Synthesis and structure of [Rh-6((PPr3)-Pr-i)(6)H-11(OH)][BAr4F](2)

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