Reversibility in the protonolysis of a β-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine

Anthony G.M. Barrett; Mark R. Crimmin; Michael S. Hill; Gabriele Kociok-Köhn; Jennifer R. Lachs; Panayiotis A. Procopiou

doi:10.1039/b717402k

Reversibility in the protonolysis of a β-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine

Anthony G.M. Barrett
, Mark R. Crimmin
, Michael S. Hill
, Gabriele Kociok-Köhn
, Jennifer R. Lachs
, Panayiotis A. Procopiou

University of Bath
Imperial College London
GlaxoSmithKline

Research output: Contribution to journal › Comment/debate › peer-review

18 Citations (SciVal)

Abstract

Protonolysis of the β-diketiminate calcium bis(trimethylsilyl)amide [(ArNC(Me)CHC(Me)NAr)Ca(N(SiMe₃)₂)(THF)] with benzylamine is reversible and forms a quantifiable equilibrium mixture.

Original language	English
Pages (from-to)	1292-1294
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	10
DOIs	https://doi.org/10.1039/b717402k
Publication status	Published - 4 Feb 2008

ASJC Scopus subject areas

General Chemistry

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10.1039/b717402k

Cite this

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title = "Reversibility in the protonolysis of a β-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine",

abstract = "Protonolysis of the β-diketiminate calcium bis(trimethylsilyl)amide [(ArNC(Me)CHC(Me)NAr)Ca(N(SiMe3)2)(THF)] with benzylamine is reversible and forms a quantifiable equilibrium mixture.",

author = "Barrett, \{Anthony G.M.\} and Crimmin, \{Mark R.\} and Hill, \{Michael S.\} and Gabriele Kociok-K{\"o}hn and Lachs, \{Jennifer R.\} and Procopiou, \{Panayiotis A.\}",

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doi = "10.1039/b717402k",

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journal = "Journal of the Chemical Society. Dalton Transactions",

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publisher = "Royal Society of Chemistry",

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AU - Barrett, Anthony G.M.

AU - Crimmin, Mark R.

AU - Hill, Michael S.

AU - Kociok-Köhn, Gabriele

AU - Lachs, Jennifer R.

AU - Procopiou, Panayiotis A.

PY - 2008/2/4

Y1 - 2008/2/4

N2 - Protonolysis of the β-diketiminate calcium bis(trimethylsilyl)amide [(ArNC(Me)CHC(Me)NAr)Ca(N(SiMe3)2)(THF)] with benzylamine is reversible and forms a quantifiable equilibrium mixture.

AB - Protonolysis of the β-diketiminate calcium bis(trimethylsilyl)amide [(ArNC(Me)CHC(Me)NAr)Ca(N(SiMe3)2)(THF)] with benzylamine is reversible and forms a quantifiable equilibrium mixture.

UR - https://www.scopus.com/pages/publications/39749148959

U2 - 10.1039/b717402k

DO - 10.1039/b717402k

M3 - Comment/debate

C2 - 18305840

AN - SCOPUS:39749148959

SN - 1477-9226

SP - 1292

EP - 1294

JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 10

ER -

Reversibility in the protonolysis of a β-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine

Abstract

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Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

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Reversibility in the protonolysis of a β-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Projects

Hydroamination of Alkenes and Alkynes with Group 2 Centred Catalysts

Cite this