Regression Analysis of properties of [Au(IPr)(CHR2)] complexes

Richard M. P. Veenboer, Luis M. Azofra, Danila Gasperini, Alba Collado, David Cordes, Alexandra M.z. Slawin, Luigi Cavallo, Steven P. Nolan

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

New [Au(IPr)(CHR 2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH 2R 2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR 2)] complexes. Variation of the R substituents on the carbanion ligands (CHR 2 -) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR 2)] complexes.

Original languageEnglish
Pages (from-to)7693-7703
Number of pages11
JournalDalton Transactions
Volume48
Issue number22
Early online date7 May 2019
DOIs
Publication statusPublished - 14 Jun 2019

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Veenboer, R. M. P., Azofra, L. M., Gasperini, D., Collado, A., Cordes, D., Slawin, A. M. Z., ... Nolan, S. P. (2019). Regression Analysis of properties of [Au(IPr)(CHR2)] complexes. Dalton Transactions , 48(22), 7693-7703. https://doi.org/10.1039/C9DT00841A

Regression Analysis of properties of [Au(IPr)(CHR2)] complexes. / Veenboer, Richard M. P. ; Azofra, Luis M.; Gasperini, Danila; Collado, Alba; Cordes, David; Slawin, Alexandra M.z.; Cavallo, Luigi; Nolan, Steven P.

In: Dalton Transactions , Vol. 48, No. 22, 14.06.2019, p. 7693-7703.

Research output: Contribution to journalArticle

Veenboer, RMP, Azofra, LM, Gasperini, D, Collado, A, Cordes, D, Slawin, AMZ, Cavallo, L & Nolan, SP 2019, 'Regression Analysis of properties of [Au(IPr)(CHR2)] complexes', Dalton Transactions , vol. 48, no. 22, pp. 7693-7703. https://doi.org/10.1039/C9DT00841A
Veenboer RMP, Azofra LM, Gasperini D, Collado A, Cordes D, Slawin AMZ et al. Regression Analysis of properties of [Au(IPr)(CHR2)] complexes. Dalton Transactions . 2019 Jun 14;48(22):7693-7703. https://doi.org/10.1039/C9DT00841A
Veenboer, Richard M. P. ; Azofra, Luis M. ; Gasperini, Danila ; Collado, Alba ; Cordes, David ; Slawin, Alexandra M.z. ; Cavallo, Luigi ; Nolan, Steven P. / Regression Analysis of properties of [Au(IPr)(CHR2)] complexes. In: Dalton Transactions . 2019 ; Vol. 48, No. 22. pp. 7693-7703.
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