Recent status and challenges in multifunctional electrocatalysis based on 2D MXenes

Srikanth Ponnada; Maryam Sadat Kiai; Demudu Babu Gorle; Rapaka S.C. Bose; Venkatachalam Rajagopal; Bhagirath Saini; Murugavel Kathiresan; Annapurna Nowduri; Rahul Singhal; Frank Marken; Manickam Anbu Kulandainathan; Karuna Kar Nanda; Rakesh K. Sharma

doi:10.1039/d2cy00428c

Recent status and challenges in multifunctional electrocatalysis based on 2D MXenes

Srikanth Ponnada, Maryam Sadat Kiai, Demudu Babu Gorle, Rapaka S.C. Bose, Venkatachalam Rajagopal, Bhagirath Saini, Murugavel Kathiresan, Annapurna Nowduri, Rahul Singhal, Frank Marken, Manickam Anbu Kulandainathan, Karuna Kar Nanda, Rakesh K. Sharma

Research output: Contribution to journal › Article › peer-review

21 Citations (SciVal)

Abstract

Due to their chemical and electrical characteristics, such as metallic conductivity, redox-activity in transition metals, high hydrophilicity, and adjustable surface properties, MXenes are emerging as important contributors to oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) catalyst development. In this review, we summarize current advances in electrocatalysis using MXene-based composite materials for the ORR, OER, and HER, and their linking processes to theoretical models. Significant factors that affect the properties of MXene based electrocatalysts, including functional groups, conductivity, and interfacial design, are discussed. Recent advances in MXene material engineering and material technology are also discussed. Finally, we have discussed the current limitations of ORR, OER, and HER electrocatalysts based on MXene composites, obstacles to their future development, and recommendations for future research efforts.

Original language	English
Pages (from-to)	4413-4441
Number of pages	29
Journal	Catalysis Science and Technology
Volume	12
Issue number	14
Early online date	14 Jun 2022
DOIs	https://doi.org/10.1039/d2cy00428c
Publication status	Published - 21 Jul 2022

Bibliographical note

Funding Information:
This review is dedicated to Professor Yury Gogotsi-Drexel University, on his 60th birthday. All the authors would like to acknowledge the Indian Institute of Technology Jodhpur-India; Indian Institute of Science-India; Centre for Materials for Electronics Technology-Thrissur-India; Istanbul Technical University, Istanbul-Turkey; CSIR-Central Electrochemical Research Institute-India; Institute of Physics-India; University of Bath-U.K; Central Connecticut State University-USA; Andhra University College of Engineering, Andhra University, Visakhapatnam-India; University Grants Commission-Government of India for resource and technical support and Dr. D. S. Kothari Postdoctoral Fellowship financial assistance to Demudu Babu Gorle. Rakesh K. Sharma and Srikanth Ponnada are grateful to SERB-CRG-India (CRG/2020/002163) and DBT (BT/PR41982/PBD/26/822/2021).

ASJC Scopus subject areas

Catalysis

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10.1039/d2cy00428c

Cite this

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title = "Recent status and challenges in multifunctional electrocatalysis based on 2D MXenes",

abstract = "Due to their chemical and electrical characteristics, such as metallic conductivity, redox-activity in transition metals, high hydrophilicity, and adjustable surface properties, MXenes are emerging as important contributors to oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) catalyst development. In this review, we summarize current advances in electrocatalysis using MXene-based composite materials for the ORR, OER, and HER, and their linking processes to theoretical models. Significant factors that affect the properties of MXene based electrocatalysts, including functional groups, conductivity, and interfacial design, are discussed. Recent advances in MXene material engineering and material technology are also discussed. Finally, we have discussed the current limitations of ORR, OER, and HER electrocatalysts based on MXene composites, obstacles to their future development, and recommendations for future research efforts.",

author = "Srikanth Ponnada and Kiai, {Maryam Sadat} and Gorle, {Demudu Babu} and Bose, {Rapaka S.C.} and Venkatachalam Rajagopal and Bhagirath Saini and Murugavel Kathiresan and Annapurna Nowduri and Rahul Singhal and Frank Marken and Kulandainathan, {Manickam Anbu} and Nanda, {Karuna Kar} and Sharma, {Rakesh K.}",

note = "Funding Information: This review is dedicated to Professor Yury Gogotsi-Drexel University, on his 60th birthday. All the authors would like to acknowledge the Indian Institute of Technology Jodhpur-India; Indian Institute of Science-India; Centre for Materials for Electronics Technology-Thrissur-India; Istanbul Technical University, Istanbul-Turkey; CSIR-Central Electrochemical Research Institute-India; Institute of Physics-India; University of Bath-U.K; Central Connecticut State University-USA; Andhra University College of Engineering, Andhra University, Visakhapatnam-India; University Grants Commission-Government of India for resource and technical support and Dr. D. S. Kothari Postdoctoral Fellowship financial assistance to Demudu Babu Gorle. Rakesh K. Sharma and Srikanth Ponnada are grateful to SERB-CRG-India (CRG/2020/002163) and DBT (BT/PR41982/PBD/26/822/2021). ",

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doi = "10.1039/d2cy00428c",

language = "English",

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T1 - Recent status and challenges in multifunctional electrocatalysis based on 2D MXenes

AU - Ponnada, Srikanth

AU - Kiai, Maryam Sadat

AU - Gorle, Demudu Babu

AU - Bose, Rapaka S.C.

AU - Rajagopal, Venkatachalam

AU - Saini, Bhagirath

AU - Kathiresan, Murugavel

AU - Nowduri, Annapurna

AU - Singhal, Rahul

AU - Marken, Frank

AU - Kulandainathan, Manickam Anbu

AU - Nanda, Karuna Kar

AU - Sharma, Rakesh K.

N1 - Funding Information: This review is dedicated to Professor Yury Gogotsi-Drexel University, on his 60th birthday. All the authors would like to acknowledge the Indian Institute of Technology Jodhpur-India; Indian Institute of Science-India; Centre for Materials for Electronics Technology-Thrissur-India; Istanbul Technical University, Istanbul-Turkey; CSIR-Central Electrochemical Research Institute-India; Institute of Physics-India; University of Bath-U.K; Central Connecticut State University-USA; Andhra University College of Engineering, Andhra University, Visakhapatnam-India; University Grants Commission-Government of India for resource and technical support and Dr. D. S. Kothari Postdoctoral Fellowship financial assistance to Demudu Babu Gorle. Rakesh K. Sharma and Srikanth Ponnada are grateful to SERB-CRG-India (CRG/2020/002163) and DBT (BT/PR41982/PBD/26/822/2021).

PY - 2022/7/21

Y1 - 2022/7/21

N2 - Due to their chemical and electrical characteristics, such as metallic conductivity, redox-activity in transition metals, high hydrophilicity, and adjustable surface properties, MXenes are emerging as important contributors to oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) catalyst development. In this review, we summarize current advances in electrocatalysis using MXene-based composite materials for the ORR, OER, and HER, and their linking processes to theoretical models. Significant factors that affect the properties of MXene based electrocatalysts, including functional groups, conductivity, and interfacial design, are discussed. Recent advances in MXene material engineering and material technology are also discussed. Finally, we have discussed the current limitations of ORR, OER, and HER electrocatalysts based on MXene composites, obstacles to their future development, and recommendations for future research efforts.

AB - Due to their chemical and electrical characteristics, such as metallic conductivity, redox-activity in transition metals, high hydrophilicity, and adjustable surface properties, MXenes are emerging as important contributors to oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) catalyst development. In this review, we summarize current advances in electrocatalysis using MXene-based composite materials for the ORR, OER, and HER, and their linking processes to theoretical models. Significant factors that affect the properties of MXene based electrocatalysts, including functional groups, conductivity, and interfacial design, are discussed. Recent advances in MXene material engineering and material technology are also discussed. Finally, we have discussed the current limitations of ORR, OER, and HER electrocatalysts based on MXene composites, obstacles to their future development, and recommendations for future research efforts.

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DO - 10.1039/d2cy00428c

M3 - Article

AN - SCOPUS:85133661091

SN - 2044-4753

VL - 12

SP - 4413

EP - 4441

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 14

ER -

Recent status and challenges in multifunctional electrocatalysis based on 2D MXenes

Abstract

Bibliographical note

ASJC Scopus subject areas

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