Reactivity of CS2 towards the anion [Mo2Cp2(CO)3(PPh2)(μ-η 2-P2)]-; synthesis and characterisation of [Mo2Cp2(CO)3{μ-η3-Ph 2PC(H)SP2S}], a complex containing an unusual CSP2S ring

John E. Davies; Martin J. Mays; Paul R. Raithby; Gregory P. Shields; Peter K. Tompkin

doi:10.1039/CC9960002051

Reactivity of CS₂ towards the anion [Mo₂Cp₂(CO)₃(PPh₂)(μ-η ²-P₂)]-; synthesis and characterisation of [Mo₂Cp₂(CO)₃{μ-η³-Ph ₂PC(H)SP₂S}], a complex containing an unusual CSP₂S ring

John E. Davies, Martin J. Mays, Paul R. Raithby, Gregory P. Shields, Peter K. Tompkin

Durham University

Research output: Contribution to journal › Article › peer-review

12 Citations (SciVal)

Abstract

The complex [Mo₂Cp₂(CO)₃(PPh₂H)(μ-η ²-P₂)] is deprotonated at -78°C by Bu^tLi; subsequent addition of an excess of CS₂ affords the novel complex [Mo₂Cp₂(CO)₃{μ-η³-Ph ₂PC(H)SP₂S}] in good to moderate yield.

Original language	English
Pages (from-to)	2051-2052
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/CC9960002051
Publication status	Published - 1 Jan 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/CC9960002051

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Reactivity of CS₂ towards the anion [Mo₂Cp₂(CO)₃(PPh₂)(μ-η ²-P₂)]-; synthesis and characterisation of [Mo₂Cp₂(CO)₃{μ-η³-Ph ₂PC(H)SP₂S}], a complex containing an unusual CSP₂S ring. / Davies, John E.; Mays, Martin J.; Raithby, Paul R. et al.
In: Chemical Communications, No. 17, 01.01.1996, p. 2051-2052.

Research output: Contribution to journal › Article › peer-review

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title = "Reactivity of CS2 towards the anion [Mo2Cp2(CO)3(PPh2)(μ-η 2-P2)]-; synthesis and characterisation of [Mo2Cp2(CO)3{μ-η3-Ph 2PC(H)SP2S}], a complex containing an unusual CSP2S ring",

abstract = "The complex [Mo2Cp2(CO)3(PPh2H)(μ-η 2-P2)] is deprotonated at -78°C by ButLi; subsequent addition of an excess of CS2 affords the novel complex [Mo2Cp2(CO)3{μ-η3-Ph 2PC(H)SP2S}] in good to moderate yield.",

author = "Davies, {John E.} and Mays, {Martin J.} and Raithby, {Paul R.} and Shields, {Gregory P.} and Tompkin, {Peter K.}",

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doi = "10.1039/CC9960002051",

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AU - Davies, John E.

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Shields, Gregory P.

AU - Tompkin, Peter K.

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N2 - The complex [Mo2Cp2(CO)3(PPh2H)(μ-η 2-P2)] is deprotonated at -78°C by ButLi; subsequent addition of an excess of CS2 affords the novel complex [Mo2Cp2(CO)3{μ-η3-Ph 2PC(H)SP2S}] in good to moderate yield.

AB - The complex [Mo2Cp2(CO)3(PPh2H)(μ-η 2-P2)] is deprotonated at -78°C by ButLi; subsequent addition of an excess of CS2 affords the novel complex [Mo2Cp2(CO)3{μ-η3-Ph 2PC(H)SP2S}] in good to moderate yield.

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Reactivity of CS₂ towards the anion [Mo₂Cp₂(CO)₃(PPh₂)(μ-η ²-P₂)]-; synthesis and characterisation of [Mo₂Cp₂(CO)₃{μ-η³-Ph ₂PC(H)SP₂S}], a complex containing an unusual CSP₂S ring

Abstract

ASJC Scopus subject areas

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