Reactivity of CS2 towards the anion [Mo2Cp2(CO)3(PPh2)(μ-η 2-P2)]-; synthesis and characterisation of [Mo2Cp2(CO)3{μ-η3-Ph 2PC(H)SP2S}], a complex containing an unusual CSP2S ring

John E. Davies, Martin J. Mays, Paul R. Raithby, Gregory P. Shields, Peter K. Tompkin

Research output: Contribution to journalArticlepeer-review

Abstract

The complex [Mo2Cp2(CO)3(PPh2H)(μ-η 2-P2)] is deprotonated at -78°C by ButLi; subsequent addition of an excess of CS2 affords the novel complex [Mo2Cp2(CO)3{μ-η3-Ph 2PC(H)SP2S}] in good to moderate yield.

Original languageEnglish
Pages (from-to)2051-2052
Number of pages2
JournalChemical Communications
Issue number17
DOIs
Publication statusPublished - 1 Jan 1996

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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