Reactivity of acryloyl chloride towards the anion [Cp2(CO)4Mo2(μ- PPhH)]-; synthesis of an unusual phosphaalkene

John E. Davies; Martin J. Mays; Paul R. Raithby; Anthony D. Woods

doi:10.1039/a907915g

Reactivity of acryloyl chloride towards the anion [Cp₂(CO)₄Mo₂(μ- PPhH)]^-; synthesis of an unusual phosphaalkene

John E. Davies, Martin J. Mays, Paul R. Raithby, Anthony D. Woods

University of Bath

Research output: Contribution to journal › Article › peer-review

19 Citations (SciVal)

Abstract

Deprotonation of the complex [Cp₂(CO)₄Mo₂(μ-PPhH)(μ-H)] by Bu(t)Li at -78 °C and subsequent addition of acryloyl chloride affords the metallophosphaalkene complex [Cp₂(CO)₄Mo₂(η¹-η²-PhP=CHMe)] in high yield; the complex exhibits cis/trans isomerism, both isomers having been crystallographically characterised.

Original language	English
Pages (from-to)	2455-2456
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/a907915g
Publication status	Published - 21 Dec 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a907915g

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abstract = "Deprotonation of the complex [Cp2(CO)4Mo2(μ-PPhH)(μ-H)] by Bu(t)Li at -78 °C and subsequent addition of acryloyl chloride affords the metallophosphaalkene complex [Cp2(CO)4Mo2(η1-η2-PhP=CHMe)] in high yield; the complex exhibits cis/trans isomerism, both isomers having been crystallographically characterised.",

author = "Davies, {John E.} and Mays, {Martin J.} and Raithby, {Paul R.} and Woods, {Anthony D.}",

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AU - Davies, John E.

AU - Mays, Martin J.

AU - Raithby, Paul R.

AU - Woods, Anthony D.

PY - 1999/12/21

Y1 - 1999/12/21

N2 - Deprotonation of the complex [Cp2(CO)4Mo2(μ-PPhH)(μ-H)] by Bu(t)Li at -78 °C and subsequent addition of acryloyl chloride affords the metallophosphaalkene complex [Cp2(CO)4Mo2(η1-η2-PhP=CHMe)] in high yield; the complex exhibits cis/trans isomerism, both isomers having been crystallographically characterised.

AB - Deprotonation of the complex [Cp2(CO)4Mo2(μ-PPhH)(μ-H)] by Bu(t)Li at -78 °C and subsequent addition of acryloyl chloride affords the metallophosphaalkene complex [Cp2(CO)4Mo2(η1-η2-PhP=CHMe)] in high yield; the complex exhibits cis/trans isomerism, both isomers having been crystallographically characterised.

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Reactivity of acryloyl chloride towards the anion [Cp₂(CO)₄Mo₂(μ- PPhH)]^-; synthesis of an unusual phosphaalkene

Abstract

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