Reactivity of a magnesium diboranate with organic nitriles

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Abstract

A series of complexes generated through reactions of the β-diketiminato magnesium diboranate species, [(BDI)Mg{(n-Bu)pinB-Bpin}] (BDI = HC{(Me)CNDipp}2; Dipp = 2,6-di-iso-propylphenyl), and a variety of organic nitriles are reported. Although, in every case, the diboranate anion acts as a surrogate source of the {Bpin} nucleophile, resulting in B–C bond formation at the electrophilic sp-hydridised nitrile carbon, the resultant compounds display a variable propensity to undergo subsequent reaction with additional nitrile equivalents. This behaviour is rationalised to be a consequence of substituent-dependent modulation in the basicity and resultant electrophilicity of magnesium-coordinated nitrile intermediates.
Original languageEnglish
Pages (from-to)1283-1292
JournalDalton Transactions
Volume50
Issue number4
Early online date11 Dec 2020
DOIs
Publication statusPublished - 28 Jan 2021

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