Reactive main group metal complexes of the neutral NNNN macrocycle, Me4TACD

Priyabrata Ghana; Louis J. Morris; Jun Okuda

doi:10.1039/d4dt03357d

Reactive main group metal complexes of the neutral NNNN macrocycle, Me₄TACD

Priyabrata Ghana
, Louis J. Morris
, Jun Okuda

Department of Chemistry

Indian Institute of Technology Kanpur
RWTH Aachen University

Research output: Contribution to journal › Review article › peer-review

2 Citations (SciVal)

Abstract

Currently, there is considerable interest in introducing molecularly defined main group metal compounds as precursors and model complexes of homogeneous catalysts for various bond cleavage and forming transformations. With a focus on the NNNN macrocyclic ligand Me₄TACD (N,N′,N′′,N′′′-tetramethyl-1,4,7,10-tetraazacyclododecane), this review summarizes the versatility of the ligand Me₄TACD for the stabilization of reactive main group s- and p-block (group 1, 2, 12-14) metals. Metal hydrides, hydrocarbyls and silyls are often monomeric and catalyze alkene hydrofunctionalisations. In contrast to the rich coordination chemistry of d- and f-block transition metals using a plethora of ligands, main group metals still leave room for new structures and reactivities, aligning with the current efforts to develop a systematic understanding in s- and p-block metal-ligand combinations.

Original language	English
Pages (from-to)	10504-10540
Number of pages	37
Journal	Dalton Transactions
Volume	54
Issue number	27
Early online date	29 May 2025
DOIs	https://doi.org/10.1039/d4dt03357d
Publication status	Published - 29 May 2025

Data Availability Statement

No primary research results, software or code have been included and no new data were generated or analysed as part of this review.

Acknowledgements

Professor Shigehiro Yamaguchi, Nagoya University, kindly provided facilities at the Research Center for Material Science to complete this manuscript.

Funding

J. O. acknowledges the Deutsche Forschungsgemeinschaft for financial support and all the former coworkers for their hard work.

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1039/d4dt03357dLicence: CC BY

Cite this

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abstract = "Currently, there is considerable interest in introducing molecularly defined main group metal compounds as precursors and model complexes of homogeneous catalysts for various bond cleavage and forming transformations. With a focus on the NNNN macrocyclic ligand Me4TACD (N,N′,N′′,N′′′-tetramethyl-1,4,7,10-tetraazacyclododecane), this review summarizes the versatility of the ligand Me4TACD for the stabilization of reactive main group s- and p-block (group 1, 2, 12-14) metals. Metal hydrides, hydrocarbyls and silyls are often monomeric and catalyze alkene hydrofunctionalisations. In contrast to the rich coordination chemistry of d- and f-block transition metals using a plethora of ligands, main group metals still leave room for new structures and reactivities, aligning with the current efforts to develop a systematic understanding in s- and p-block metal-ligand combinations.",

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AB - Currently, there is considerable interest in introducing molecularly defined main group metal compounds as precursors and model complexes of homogeneous catalysts for various bond cleavage and forming transformations. With a focus on the NNNN macrocyclic ligand Me4TACD (N,N′,N′′,N′′′-tetramethyl-1,4,7,10-tetraazacyclododecane), this review summarizes the versatility of the ligand Me4TACD for the stabilization of reactive main group s- and p-block (group 1, 2, 12-14) metals. Metal hydrides, hydrocarbyls and silyls are often monomeric and catalyze alkene hydrofunctionalisations. In contrast to the rich coordination chemistry of d- and f-block transition metals using a plethora of ligands, main group metals still leave room for new structures and reactivities, aligning with the current efforts to develop a systematic understanding in s- and p-block metal-ligand combinations.

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