Reactions of triosmium clusters with organic azides; x-ray crystal structures of [Os3(CO)10(NCMe)(N3COPh)], [Os3(μ-H)(CO)10(HN3Ph)], and [Os3(μ-H)2(CO)9(μ3-NPh)]

Kevin Burgess; Brian F. G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1016/S0022-328X(00)93183-8

Reactions of triosmium clusters with organic azides; x-ray crystal structures of [Os₃(CO)₁₀(NCMe)(N₃COPh)], [Os₃(μ-H)(CO)₁₀(HN₃Ph)], and [Os₃(μ-H)₂(CO)₉(μ₃-NPh)]

Kevin Burgess, Brian F. G. Johnson, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Organic azides [N₃R] react with [Os₃(CO)₁₁(NCMe)] and with [Os₃(μ-H)₂(CO)₁₀] to form [Os₃(CO)₁₀(NCMe)(N₃COR)] (R Ph) and [Os₃(μ-H)(CO)₁₀(HN₃R)] (R Ph, n-Bu, CH₂Ph, cyclo-C₆H₁₁), respectively; the latter may be converted to [Os₃(μ-H)₂(CO)₉(μ₃-NR)] by thermolysis; the molecular structure of the phenyl derivative of each class of compound has been confirmed by x-ray analysis.

Original language	English
Pages (from-to)	C40-C44
Journal	Journal of Organometallic Chemistry
Volume	224
Issue number	4
DOIs	https://doi.org/10.1016/S0022-328X(00)93183-8
Publication status	Published - 26 Jan 1982

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)93183-8

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Reactions of triosmium clusters with organic azides; x-ray crystal structures of [Os₃(CO)₁₀(NCMe)(N₃COPh)], [Os₃(μ-H)(CO)₁₀(HN₃Ph)], and [Os₃(μ-H)₂(CO)₉(μ₃-NPh)]. / Burgess, Kevin; Johnson, Brian F. G.; Lewis, Jack et al.
In: Journal of Organometallic Chemistry, Vol. 224, No. 4, 26.01.1982, p. C40-C44.

Research output: Contribution to journal › Article › peer-review

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title = "Reactions of triosmium clusters with organic azides; x-ray crystal structures of [Os3(CO)10(NCMe)(N3COPh)], [Os3(μ-H)(CO)10(HN3Ph)], and [Os3(μ-H)2(CO)9(μ3-NPh)]",

abstract = "Organic azides [N3R] react with [Os3(CO)11(NCMe)] and with [Os3(μ-H)2(CO)10] to form [Os3(CO)10(NCMe)(N3COR)] (R Ph) and [Os3(μ-H)(CO)10(HN3R)] (R Ph, n-Bu, CH2Ph, cyclo-C6H11), respectively; the latter may be converted to [Os3(μ-H)2(CO)9(μ3-NR)] by thermolysis; the molecular structure of the phenyl derivative of each class of compound has been confirmed by x-ray analysis.",

author = "Kevin Burgess and Johnson, \{Brian F. G.\} and Jack Lewis and Raithby, \{Paul R.\}",

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T1 - Reactions of triosmium clusters with organic azides; x-ray crystal structures of [Os3(CO)10(NCMe)(N3COPh)], [Os3(μ-H)(CO)10(HN3Ph)], and [Os3(μ-H)2(CO)9(μ3-NPh)]

AU - Burgess, Kevin

AU - Johnson, Brian F. G.

AU - Lewis, Jack

AU - Raithby, Paul R.

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N2 - Organic azides [N3R] react with [Os3(CO)11(NCMe)] and with [Os3(μ-H)2(CO)10] to form [Os3(CO)10(NCMe)(N3COR)] (R Ph) and [Os3(μ-H)(CO)10(HN3R)] (R Ph, n-Bu, CH2Ph, cyclo-C6H11), respectively; the latter may be converted to [Os3(μ-H)2(CO)9(μ3-NR)] by thermolysis; the molecular structure of the phenyl derivative of each class of compound has been confirmed by x-ray analysis.

AB - Organic azides [N3R] react with [Os3(CO)11(NCMe)] and with [Os3(μ-H)2(CO)10] to form [Os3(CO)10(NCMe)(N3COR)] (R Ph) and [Os3(μ-H)(CO)10(HN3R)] (R Ph, n-Bu, CH2Ph, cyclo-C6H11), respectively; the latter may be converted to [Os3(μ-H)2(CO)9(μ3-NR)] by thermolysis; the molecular structure of the phenyl derivative of each class of compound has been confirmed by x-ray analysis.

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ER -

Reactions of triosmium clusters with organic azides; x-ray crystal structures of [Os₃(CO)₁₀(NCMe)(N₃COPh)], [Os₃(μ-H)(CO)₁₀(HN₃Ph)], and [Os₃(μ-H)₂(CO)₉(μ₃-NPh)]

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