Reactions of [Os3H2(CO)10] and [Os3H(CO)11]-with [N3SiMe3] and the formation of...

Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Stephen W. Sankey

doi:10.1016/S0022-328X(00)87091-6

Reactions of [Os₃H₂(CO)₁₀] and [Os₃H(CO)₁₁]^-with [N₃SiMe₃] and the formation of...

Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Stephen W. Sankey

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Title full: Reactions of [Os₃H₂(CO)₁₀] and [Os₃H(CO)₁₁]^-with [N₃SiMe₃] and the formation of [Os₃H(CO)₁₀(μ-NHPh)] using [Os₃(CO)₁₁(NCMe)]; x-ray crystal structures of [Os₃(μ-H)(CO)₁₀(η-N₃H₂)] and [Os₃(μ-H)(CO)₁₀(μ-NHSiMe₃)]. Reaction of the cluster [Os₃H₂(CO)₁₀] with (N₃SiMe₃) yields the triazenido species [Os₃(μ-H)(CO)₁₀(η-N₃H₂)] (I) which, upon reflux, loses N₂ to give [Os₃(μ-H)(CO)₁₀(μ-NH₂)] (II); the capped species [Os₃](μ-H)₂(CO)₉(μ₃-NP h)] may be obtained by reaction of [Os₃(CO)₁₁(NCMe)] with NH₂Ph and subsequent pyrolysis of the high yield product [Os₃(μ-H)(CO)₁₀(μ-NHPh)]; with [Os₃H(CO)₁₁]^- trimethylsilylazide yields [Os₃(μ-H)(CO)₁₀(μ-NHSiMe₃)] (III); the structures of I and III have been confirmed by single-crystal X-ray analyses.

Original language	English
Pages (from-to)	135-138
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	228
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)87091-6
Publication status	Published - 23 Mar 1982

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/S0022-328X(00)87091-6

Cite this

@article{c85c46cf7e944f58a5a241df83f0aa45,

title = "Reactions of [Os3H2(CO)10] and [Os3H(CO)11]-with [N3SiMe3] and the formation of...",

abstract = "Title full: Reactions of [Os3H2(CO)10] and [Os3H(CO)11]-with [N3SiMe3] and the formation of [Os3H(CO)10(μ-NHPh)] using [Os3(CO)11(NCMe)]; x-ray crystal structures of [Os3(μ-H)(CO)10(η-N3H 2)] and [Os3(μ-H)(CO)10(μ-NHSiMe3)]. Reaction of the cluster [Os3H2(CO)10] with (N3SiMe3) yields the triazenido species [Os3(μ-H)(CO)10(η-N3H2 )] (I) which, upon reflux, loses N2 to give [Os3(μ-H)(CO)10(μ-NH2)] (II); the capped species [Os3](μ-H)2(CO)9(μ3-NP h)] may be obtained by reaction of [Os3(CO)11(NCMe)] with NH2Ph and subsequent pyrolysis of the high yield product [Os3(μ-H)(CO)10(μ-NHPh)]; with [Os3H(CO)11]- trimethylsilylazide yields [Os3(μ-H)(CO)10(μ-NHSiMe3)] (III); the structures of I and III have been confirmed by single-crystal X-ray analyses.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\} and Sankey, \{Stephen W.\}",

year = "1982",

month = mar,

day = "23",

doi = "10.1016/S0022-328X(00)87091-6",

language = "English",

volume = "228",

pages = "135--138",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Reactions of [Os3H2(CO)10] and [Os3H(CO)11]-with [N3SiMe3] and the formation of...

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Sankey, Stephen W.

PY - 1982/3/23

Y1 - 1982/3/23

N2 - Title full: Reactions of [Os3H2(CO)10] and [Os3H(CO)11]-with [N3SiMe3] and the formation of [Os3H(CO)10(μ-NHPh)] using [Os3(CO)11(NCMe)]; x-ray crystal structures of [Os3(μ-H)(CO)10(η-N3H 2)] and [Os3(μ-H)(CO)10(μ-NHSiMe3)]. Reaction of the cluster [Os3H2(CO)10] with (N3SiMe3) yields the triazenido species [Os3(μ-H)(CO)10(η-N3H2 )] (I) which, upon reflux, loses N2 to give [Os3(μ-H)(CO)10(μ-NH2)] (II); the capped species [Os3](μ-H)2(CO)9(μ3-NP h)] may be obtained by reaction of [Os3(CO)11(NCMe)] with NH2Ph and subsequent pyrolysis of the high yield product [Os3(μ-H)(CO)10(μ-NHPh)]; with [Os3H(CO)11]- trimethylsilylazide yields [Os3(μ-H)(CO)10(μ-NHSiMe3)] (III); the structures of I and III have been confirmed by single-crystal X-ray analyses.

AB - Title full: Reactions of [Os3H2(CO)10] and [Os3H(CO)11]-with [N3SiMe3] and the formation of [Os3H(CO)10(μ-NHPh)] using [Os3(CO)11(NCMe)]; x-ray crystal structures of [Os3(μ-H)(CO)10(η-N3H 2)] and [Os3(μ-H)(CO)10(μ-NHSiMe3)]. Reaction of the cluster [Os3H2(CO)10] with (N3SiMe3) yields the triazenido species [Os3(μ-H)(CO)10(η-N3H2 )] (I) which, upon reflux, loses N2 to give [Os3(μ-H)(CO)10(μ-NH2)] (II); the capped species [Os3](μ-H)2(CO)9(μ3-NP h)] may be obtained by reaction of [Os3(CO)11(NCMe)] with NH2Ph and subsequent pyrolysis of the high yield product [Os3(μ-H)(CO)10(μ-NHPh)]; with [Os3H(CO)11]- trimethylsilylazide yields [Os3(μ-H)(CO)10(μ-NHSiMe3)] (III); the structures of I and III have been confirmed by single-crystal X-ray analyses.

UR - http://www.scopus.com/inward/record.url?scp=0001293012&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)87091-6

DO - 10.1016/S0022-328X(00)87091-6

M3 - Article

AN - SCOPUS:0001293012

SN - 0022-328X

VL - 228

SP - 135

EP - 138

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Reactions of [Os₃H₂(CO)₁₀] and [Os₃H(CO)₁₁]^-with [N₃SiMe₃] and the formation of...

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this