Abstract
The reaction of (diphenylmethylene)hydrazone or 1,4-bis-hydrazone-ylidene(phenylmethyl)benzene with Lewis acidic boranes B(2,4,6-F3C6H2)3 or B(3,4,5-F3C6H2)3 generates the Lewis acid-base adducts. Alternatively, when (9H-fluoren-9-ylidene)hydrazone is employed several products were isolated including 1,2-di(9H-fluoren-9-ylidene)hydrazone, the 2:1 borane adduct of NH2-NH2 and the 1-(diarylboraneyl)-2-(9H-fluoren-9-ylidene)hydrazone in which one ArH group has been eliminated. The benzhydrazide starting material also initially gives an adduct when reacted with Lewis acidic boranes which upon heating eliminates ArH generating a CON2B heterocycle.
Original language | English |
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Pages (from-to) | 12391-12395 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 48 |
Issue number | 33 |
Early online date | 9 Aug 2019 |
DOIs | |
Publication status | Published - 7 Sept 2019 |
ASJC Scopus subject areas
- Inorganic Chemistry