Reactions of CS2 with metal cluster carbonyls of the iron triad: synthesis and x-ray structure of Os3(CO)8(CS)S2

Peter V. Broadhurst; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1016/S0022-328X(00)86674-7

Reactions of CS₂ with metal cluster carbonyls of the iron triad: synthesis and x-ray structure of Os₃(CO)₈(CS)S₂

Peter V. Broadhurst, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of Os₃(CO)₁₂ with CS₂ in hexane at 130°C under 10 atm. CO/Ar (1/1) pressure gives Os₃(CO)₈(CS)S₂ as the major hexane eluted product. This has been fully characterised by spectroscopic and single crystal X-ray crystallographic techniques.

Original language	English
Pages (from-to)	C35-C38
Journal	Journal of Organometallic Chemistry
Volume	194
Issue number	2
DOIs	https://doi.org/10.1016/S0022-328X(00)86674-7
Publication status	Published - 29 Jul 1980

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)86674-7

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title = "Reactions of CS2 with metal cluster carbonyls of the iron triad: synthesis and x-ray structure of Os3(CO)8(CS)S2",

abstract = "The reaction of Os3(CO)12 with CS2 in hexane at 130°C under 10 atm. CO/Ar (1/1) pressure gives Os3(CO)8(CS)S2 as the major hexane eluted product. This has been fully characterised by spectroscopic and single crystal X-ray crystallographic techniques.",

author = "Broadhurst, \{Peter V.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\}",

year = "1980",

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T2 - synthesis and x-ray structure of Os3(CO)8(CS)S2

AU - Broadhurst, Peter V.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1980/7/29

Y1 - 1980/7/29

N2 - The reaction of Os3(CO)12 with CS2 in hexane at 130°C under 10 atm. CO/Ar (1/1) pressure gives Os3(CO)8(CS)S2 as the major hexane eluted product. This has been fully characterised by spectroscopic and single crystal X-ray crystallographic techniques.

AB - The reaction of Os3(CO)12 with CS2 in hexane at 130°C under 10 atm. CO/Ar (1/1) pressure gives Os3(CO)8(CS)S2 as the major hexane eluted product. This has been fully characterised by spectroscopic and single crystal X-ray crystallographic techniques.

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U2 - 10.1016/S0022-328X(00)86674-7

DO - 10.1016/S0022-328X(00)86674-7

M3 - Article

AN - SCOPUS:4244054594

SN - 0022-328X

VL - 194

SP - C35-C38

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -

Reactions of CS₂ with metal cluster carbonyls of the iron triad: synthesis and x-ray structure of Os₃(CO)₈(CS)S₂

Abstract

ASJC Scopus subject areas

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