TY - JOUR
T1 - Reactions of CS2 with metal cluster carbonyls of the iron triad; Synthesis and x-ray structure of [Fe4(CO)12(GS)S]
AU - Broadhurst, Peter V.
AU - Johnson, Brian F.G.
AU - Lewis, Jack
AU - Raithby, Paul R.
PY - 1980
Y1 - 1980
N2 - Reaction of [Fe3(CO)12] with CS2 in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe4(CO)12(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.
AB - Reaction of [Fe3(CO)12] with CS2 in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe4(CO)12(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.
UR - http://www.scopus.com/inward/record.url?scp=37049112647&partnerID=8YFLogxK
U2 - 10.1039/c39800000812
DO - 10.1039/c39800000812
M3 - Article
AN - SCOPUS:37049112647
SN - 0022-4936
SP - 812
EP - 813
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 17
ER -