Reactions of CS2 with metal cluster carbonyls of the iron triad; Synthesis and x-ray structure of [Fe4(CO)12(GS)S]

Peter V. Broadhurst; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1039/c39800000812

Reactions of CS₂ with metal cluster carbonyls of the iron triad; Synthesis and x-ray structure of [Fe₄(CO)₁₂(GS)S]

Peter V. Broadhurst
, Brian F.G. Johnson
, Jack Lewis
, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [Fe₃(CO)₁₂] with CS₂ in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe₄(CO)₁₂(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.

Original language	English
Pages (from-to)	812-813
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/c39800000812
Publication status	Published - 1980

ASJC Scopus subject areas

Molecular Medicine

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title = "Reactions of CS2 with metal cluster carbonyls of the iron triad; Synthesis and x-ray structure of [Fe4(CO)12(GS)S]",

abstract = "Reaction of [Fe3(CO)12] with CS2 in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe4(CO)12(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.",

author = "Broadhurst, \{Peter V.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\}",

year = "1980",

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journal = "Journal of the Chemical Society, Chemical Communications",

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AU - Broadhurst, Peter V.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1980

Y1 - 1980

N2 - Reaction of [Fe3(CO)12] with CS2 in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe4(CO)12(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.

AB - Reaction of [Fe3(CO)12] with CS2 in hexane, at 80 °C, under moderate CO/Ar pressure gives, as one of the main products, [Fe4(CO)12(CS)S], which has been shown by a single crystal X-ray analysis to contain a thiocarbonyl ligand co-ordinated to the cluster in a novel bonding mode.

UR - https://www.scopus.com/pages/publications/37049112647

U2 - 10.1039/c39800000812

DO - 10.1039/c39800000812

M3 - Article

AN - SCOPUS:37049112647

SN - 0022-4936

SP - 812

EP - 813

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Reactions of CS₂ with metal cluster carbonyls of the iron triad; Synthesis and x-ray structure of [Fe₄(CO)₁₂(GS)S]

Abstract

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