Reactions of CS2 with metal cluster carbonyls of the iron triad: Synthesis and x-ray crystal structure of [Fe4(CO) 12(C2S4)]

Peter V. Broadhurst; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1039/C39820000140

Reactions of CS₂ with metal cluster carbonyls of the iron triad: Synthesis and x-ray crystal structure of [Fe₄(CO) ₁₂(C₂S₄)]

Peter V. Broadhurst
, Brian F.G. Johnson
, Jack Lewis
, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Dodecacarbonyltri-iron, [Fe₃(CO)₁₂], reacts with an excess of CS₂ in hexane at 80°C under a CO-Ar atmosphere (1 : 1, pressure ca. 10 atm) to give a number of products including, in low yield, [Fe₄(CO)₁₂(C₂S₄)] which, on the basis of a single-crystal X-ray analysis, has been shown to contain two Fe ₂(CO)₆ units bridged by a C₂S₄ unit which may be regarded as a derivative of ethenetetrathiol.

Original language	English
Pages (from-to)	140-141
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/C39820000140
Publication status	Published - 1982

ASJC Scopus subject areas

Molecular Medicine

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title = "Reactions of CS2 with metal cluster carbonyls of the iron triad: Synthesis and x-ray crystal structure of [Fe4(CO) 12(C2S4)]",

abstract = "Dodecacarbonyltri-iron, [Fe3(CO)12], reacts with an excess of CS2 in hexane at 80°C under a CO-Ar atmosphere (1 : 1, pressure ca. 10 atm) to give a number of products including, in low yield, [Fe4(CO)12(C2S4)] which, on the basis of a single-crystal X-ray analysis, has been shown to contain two Fe 2(CO)6 units bridged by a C2S4 unit which may be regarded as a derivative of ethenetetrathiol.",

author = "Broadhurst, \{Peter V.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\}",

year = "1982",

doi = "10.1039/C39820000140",

language = "English",

pages = "140--141",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

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T1 - Reactions of CS2 with metal cluster carbonyls of the iron triad

T2 - Synthesis and x-ray crystal structure of [Fe4(CO) 12(C2S4)]

AU - Broadhurst, Peter V.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1982

Y1 - 1982

N2 - Dodecacarbonyltri-iron, [Fe3(CO)12], reacts with an excess of CS2 in hexane at 80°C under a CO-Ar atmosphere (1 : 1, pressure ca. 10 atm) to give a number of products including, in low yield, [Fe4(CO)12(C2S4)] which, on the basis of a single-crystal X-ray analysis, has been shown to contain two Fe 2(CO)6 units bridged by a C2S4 unit which may be regarded as a derivative of ethenetetrathiol.

AB - Dodecacarbonyltri-iron, [Fe3(CO)12], reacts with an excess of CS2 in hexane at 80°C under a CO-Ar atmosphere (1 : 1, pressure ca. 10 atm) to give a number of products including, in low yield, [Fe4(CO)12(C2S4)] which, on the basis of a single-crystal X-ray analysis, has been shown to contain two Fe 2(CO)6 units bridged by a C2S4 unit which may be regarded as a derivative of ethenetetrathiol.

UR - https://www.scopus.com/pages/publications/37049110670

U2 - 10.1039/C39820000140

DO - 10.1039/C39820000140

M3 - Article

AN - SCOPUS:37049110670

SN - 0022-4936

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EP - 141

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 2

ER -

Reactions of CS₂ with metal cluster carbonyls of the iron triad: Synthesis and x-ray crystal structure of [Fe₄(CO) ₁₂(C₂S₄)]

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