TY - JOUR
T1 - Reactions of CS2 with metal cluster carbonyls of the iron triad
T2 - Synthesis and x-ray crystal structure of [Fe4(CO) 12(C2S4)]
AU - Broadhurst, Peter V.
AU - Johnson, Brian F.G.
AU - Lewis, Jack
AU - Raithby, Paul R.
PY - 1982
Y1 - 1982
N2 - Dodecacarbonyltri-iron, [Fe3(CO)12], reacts with an excess of CS2 in hexane at 80°C under a CO-Ar atmosphere (1 : 1, pressure ca. 10 atm) to give a number of products including, in low yield, [Fe4(CO)12(C2S4)] which, on the basis of a single-crystal X-ray analysis, has been shown to contain two Fe 2(CO)6 units bridged by a C2S4 unit which may be regarded as a derivative of ethenetetrathiol.
AB - Dodecacarbonyltri-iron, [Fe3(CO)12], reacts with an excess of CS2 in hexane at 80°C under a CO-Ar atmosphere (1 : 1, pressure ca. 10 atm) to give a number of products including, in low yield, [Fe4(CO)12(C2S4)] which, on the basis of a single-crystal X-ray analysis, has been shown to contain two Fe 2(CO)6 units bridged by a C2S4 unit which may be regarded as a derivative of ethenetetrathiol.
UR - http://www.scopus.com/inward/record.url?scp=37049110670&partnerID=8YFLogxK
U2 - 10.1039/C39820000140
DO - 10.1039/C39820000140
M3 - Article
AN - SCOPUS:37049110670
SN - 0022-4936
SP - 140
EP - 141
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 2
ER -