Reactions of β-diketiminate-stabilized calcium amides with 9-borabicyclo[3.3.1]nonane (9-BBN)

Anthony G.M. Barrett; Mark R. Crimmin; Michael S. Hill; Peter B. Hitchcock; Panayiotis A. Procopiou

doi:10.1021/om070083t

Reactions of β-diketiminate-stabilized calcium amides with 9-borabicyclo[3.3.1]nonane (9-BBN)

Anthony G.M. Barrett, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou

Research output: Contribution to journal › Article › peer-review

48 Citations (SciVal)

Abstract

The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate- stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.

Original language	English
Pages (from-to)	4076-4079
Number of pages	4
Journal	Organometallics
Volume	26
Issue number	16
DOIs	https://doi.org/10.1021/om070083t
Publication status	Published - 30 Jul 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om070083t

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abstract = "The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate- stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.",

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AU - Barrett, Anthony G.M.

AU - Crimmin, Mark R.

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Procopiou, Panayiotis A.

PY - 2007/7/30

Y1 - 2007/7/30

N2 - The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate- stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.

AB - The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate- stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.

UR - https://www.scopus.com/pages/publications/34547819187

U2 - 10.1021/om070083t

DO - 10.1021/om070083t

M3 - Article

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JO - Organometallics

JF - Organometallics

IS - 16

ER -

Reactions of β-diketiminate-stabilized calcium amides with 9-borabicyclo[3.3.1]nonane (9-BBN)

Abstract

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