Reactions of β-diketiminate-stabilized calcium amides with 9-borabicyclo[3.3.1]nonane (9-BBN)

Anthony G.M. Barrett, Mark R. Crimmin, Michael S. Hill, Peter B. Hitchcock, Panayiotis A. Procopiou

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Abstract

The reaction of a β-diketiminate-stabilized calcium diphenylamide with the dialkylborane 9-BBN allows the synthesis of a β-diketiminate- stabilized calcium borohydride along with an amidoborane reaction coproduct via a likely σ-bond metathesis mechanism.

Original languageEnglish
Pages (from-to)4076-4079
Number of pages4
JournalOrganometallics
Volume26
Issue number16
DOIs
Publication statusPublished - 30 Jul 2007

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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