Reaction of the unsaturated mixed metal cluster [Os3(μ-H)(CO) 10-(μ-AuPR3)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os 3(CO)10(μ-AuPEt3)2]

Kevin Burgess; Brian F.G. Johnson; David A. Kaner; Jack Lewis; Paul R. Raithby; S. N.Azman B. Syed-Mustaffa

doi:10.1039/C39830000455

Reaction of the unsaturated mixed metal cluster [Os₃(μ-H)(CO) ₁₀-(μ-AuPR₃)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os ₃(CO)₁₀(μ-AuPEt₃)₂]

Kevin Burgess
, Brian F.G. Johnson
, David A. Kaner
, Jack Lewis
, Paul R. Raithby
, S. N.Azman B. Syed-Mustaffa

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster [Os₃(CO)₁₀(AuPR₃) ₂](R=Ph, Et) may be prepared by the decarbonylation of [Os ₃(CO)₁₁(AuPR₃)₂], or by the direct reaction of [Os₃H(CO)₁₁]^- or [Os ₃(CO)₁₁]^2- with two equivalents of Au(PR ₃)Cl; an X-ray analysis of [Os₃(CO)₁₀(AuPR ₃)₂] shows that both 'AuPR₃' groups bridge the same short edge of the Os₃ triangle.

Original language	English
Pages (from-to)	455-457
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/C39830000455
Publication status	Published - 31 Dec 1983

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39830000455

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Burgess, K., Johnson, B. F. G., Kaner, D. A., Lewis, J., Raithby, P. R., & Syed-Mustaffa, S. N. A. B. (1983). Reaction of the unsaturated mixed metal cluster [Os₃(μ-H)(CO) ₁₀-(μ-AuPR₃)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os ₃(CO)₁₀(μ-AuPEt₃)₂]. Journal of the Chemical Society, Chemical Communications, (8), 455-457. https://doi.org/10.1039/C39830000455

Reaction of the unsaturated mixed metal cluster [Os₃(μ-H)(CO) ₁₀-(μ-AuPR₃)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os ₃(CO)₁₀(μ-AuPEt₃)₂]. / Burgess, Kevin; Johnson, Brian F.G.; Kaner, David A. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 8, 31.12.1983, p. 455-457.

Research output: Contribution to journal › Article › peer-review

Burgess, K, Johnson, BFG, Kaner, DA, Lewis, J, Raithby, PR & Syed-Mustaffa, SNAB 1983, 'Reaction of the unsaturated mixed metal cluster [Os₃(μ-H)(CO) ₁₀-(μ-AuPR₃)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os ₃(CO)₁₀(μ-AuPEt₃)₂]', Journal of the Chemical Society, Chemical Communications, no. 8, pp. 455-457. https://doi.org/10.1039/C39830000455

Burgess K, Johnson BFG, Kaner DA, Lewis J, Raithby PR, Syed-Mustaffa SNAB. Reaction of the unsaturated mixed metal cluster [Os₃(μ-H)(CO) ₁₀-(μ-AuPR₃)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os ₃(CO)₁₀(μ-AuPEt₃)₂]. Journal of the Chemical Society, Chemical Communications. 1983 Dec 31;(8):455-457. doi: 10.1039/C39830000455

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title = "Reaction of the unsaturated mixed metal cluster [Os3(μ-H)(CO) 10-(μ-AuPR3)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os 3(CO)10(μ-AuPEt3)2]",

abstract = "The cluster [Os3(CO)10(AuPR3) 2](R=Ph, Et) may be prepared by the decarbonylation of [Os 3(CO)11(AuPR3)2], or by the direct reaction of [Os3H(CO)11]- or [Os 3(CO)11]2- with two equivalents of Au(PR 3)Cl; an X-ray analysis of [Os3(CO)10(AuPR 3)2] shows that both 'AuPR3' groups bridge the same short edge of the Os3 triangle.",

author = "Kevin Burgess and Johnson, \{Brian F.G.\} and Kaner, \{David A.\} and Jack Lewis and Raithby, \{Paul R.\} and Syed-Mustaffa, \{S. N.Azman B.\}",

year = "1983",

month = dec,

day = "31",

doi = "10.1039/C39830000455",

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AU - Burgess, Kevin

AU - Johnson, Brian F.G.

AU - Kaner, David A.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Syed-Mustaffa, S. N.Azman B.

PY - 1983/12/31

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N2 - The cluster [Os3(CO)10(AuPR3) 2](R=Ph, Et) may be prepared by the decarbonylation of [Os 3(CO)11(AuPR3)2], or by the direct reaction of [Os3H(CO)11]- or [Os 3(CO)11]2- with two equivalents of Au(PR 3)Cl; an X-ray analysis of [Os3(CO)10(AuPR 3)2] shows that both 'AuPR3' groups bridge the same short edge of the Os3 triangle.

AB - The cluster [Os3(CO)10(AuPR3) 2](R=Ph, Et) may be prepared by the decarbonylation of [Os 3(CO)11(AuPR3)2], or by the direct reaction of [Os3H(CO)11]- or [Os 3(CO)11]2- with two equivalents of Au(PR 3)Cl; an X-ray analysis of [Os3(CO)10(AuPR 3)2] shows that both 'AuPR3' groups bridge the same short edge of the Os3 triangle.

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ER -

Reaction of the unsaturated mixed metal cluster [Os₃(μ-H)(CO) ₁₀-(μ-AuPR₃)] (R=Ph, Et) with carbon monoxide and the chemistry of the products; The x-ray crystal structure of [Os ₃(CO)₁₀(μ-AuPEt₃)₂]

Abstract

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