Reaction of [Os5(CO)15H2] with acetylenes; x-ray crystal structures of [Os5(CO)15H 2(CCPh)] and [Os5(CO)13(PhCCPh)2]

David H. Farrar; Glyn R. John; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Maria J. Rosales

doi:10.1039/c39810000886

Reaction of [Os₅(CO)₁₅H₂] with acetylenes; x-ray crystal structures of [Os₅(CO)₁₅H ₂(CCPh)] and [Os₅(CO)₁₃(PhCCPh)₂]

David H. Farrar, Glyn R. John, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Maria J. Rosales

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The dihydrido-cluster [Os₅(CO)₁₅H₂] reacts with R¹C≡CR² [R¹ = H, R² = Ph; R¹ = R² = Ph] to produce a number of acetylenic cluster complexes based on the Os₅ unit, two of which have been characterised spectroscopically and by single crystal X-ray analyses as [Os ₅(CO)₁₅H₂(CCPh)] and [Os₅(CO) ₁₃(PhCCPh)₂], containing a 'wing-tip bridged butterfly' and an 'edge-bridged butterfly' metal framework, respectively.

Original language	English
Pages (from-to)	886-888
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/c39810000886
Publication status	Published - 1981

ASJC Scopus subject areas

Molecular Medicine

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title = "Reaction of [Os5(CO)15H2] with acetylenes; x-ray crystal structures of [Os5(CO)15H 2(CCPh)] and [Os5(CO)13(PhCCPh)2]",

abstract = "The dihydrido-cluster [Os5(CO)15H2] reacts with R1C≡CR2 [R1 = H, R2 = Ph; R1 = R2 = Ph] to produce a number of acetylenic cluster complexes based on the Os5 unit, two of which have been characterised spectroscopically and by single crystal X-ray analyses as [Os 5(CO)15H2(CCPh)] and [Os5(CO) 13(PhCCPh)2], containing a 'wing-tip bridged butterfly' and an 'edge-bridged butterfly' metal framework, respectively.",

author = "Farrar, \{David H.\} and John, \{Glyn R.\} and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\} and Rosales, \{Maria J.\}",

year = "1981",

doi = "10.1039/c39810000886",

language = "English",

pages = "886--888",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "17",

}

TY - JOUR

T1 - Reaction of [Os5(CO)15H2] with acetylenes; x-ray crystal structures of [Os5(CO)15H 2(CCPh)] and [Os5(CO)13(PhCCPh)2]

AU - Farrar, David H.

AU - John, Glyn R.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Rosales, Maria J.

PY - 1981

Y1 - 1981

N2 - The dihydrido-cluster [Os5(CO)15H2] reacts with R1C≡CR2 [R1 = H, R2 = Ph; R1 = R2 = Ph] to produce a number of acetylenic cluster complexes based on the Os5 unit, two of which have been characterised spectroscopically and by single crystal X-ray analyses as [Os 5(CO)15H2(CCPh)] and [Os5(CO) 13(PhCCPh)2], containing a 'wing-tip bridged butterfly' and an 'edge-bridged butterfly' metal framework, respectively.

AB - The dihydrido-cluster [Os5(CO)15H2] reacts with R1C≡CR2 [R1 = H, R2 = Ph; R1 = R2 = Ph] to produce a number of acetylenic cluster complexes based on the Os5 unit, two of which have been characterised spectroscopically and by single crystal X-ray analyses as [Os 5(CO)15H2(CCPh)] and [Os5(CO) 13(PhCCPh)2], containing a 'wing-tip bridged butterfly' and an 'edge-bridged butterfly' metal framework, respectively.

UR - http://www.scopus.com/inward/record.url?scp=37049104514&partnerID=8YFLogxK

U2 - 10.1039/c39810000886

DO - 10.1039/c39810000886

M3 - Article

AN - SCOPUS:37049104514

SN - 0022-4936

SP - 886

EP - 888

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 17

ER -

Reaction of [Os₅(CO)₁₅H₂] with acetylenes; x-ray crystal structures of [Os₅(CO)₁₅H ₂(CCPh)] and [Os₅(CO)₁₃(PhCCPh)₂]

Abstract

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