Reaction of Os3H2(CO)9(C6H4) with diphenylacetylene: the formation and structural characterisation of Os3(CO)7(C6H4)[PhCC(H)Ph]2

Hong Chen; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby

doi:10.1016/0022-328X(89)88086-6

Reaction of Os₃H₂(CO)₉(C₆H₄) with diphenylacetylene: the formation and structural characterisation of Os₃(CO)₇(C₆H₄)[PhCC(H)Ph]₂

Hong Chen, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of the 'benzyne' cluster Os₃H₂(CO)₉(C₆H₄) with diphenylacetylene affords the new compound Os₃(CO)₇(C₆H₄)[PhCC(H)Ph]₂; a single crystal X-ray analysis of this product shows that two PhCC(H)Ph units and the benzyne moiety are bonded to the Os₃ core as separate ligands, and that under these conditions there is no ligand condensation.

Original language	English
Pages (from-to)	C7-C10
Journal	Journal of Organometallic Chemistry
Volume	376
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(89)88086-6
Publication status	Published - 24 Oct 1989

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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abstract = "The reaction of the 'benzyne' cluster Os3H2(CO)9(C6H4) with diphenylacetylene affords the new compound Os3(CO)7(C6H4)[PhCC(H)Ph]2; a single crystal X-ray analysis of this product shows that two PhCC(H)Ph units and the benzyne moiety are bonded to the Os3 core as separate ligands, and that under these conditions there is no ligand condensation.",

author = "Hong Chen and Johnson, {Brian F.G.} and Jack Lewis and Raithby, {Paul R.}",

year = "1989",

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T2 - the formation and structural characterisation of Os3(CO)7(C6H4)[PhCC(H)Ph]2

AU - Chen, Hong

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1989/10/24

Y1 - 1989/10/24

N2 - The reaction of the 'benzyne' cluster Os3H2(CO)9(C6H4) with diphenylacetylene affords the new compound Os3(CO)7(C6H4)[PhCC(H)Ph]2; a single crystal X-ray analysis of this product shows that two PhCC(H)Ph units and the benzyne moiety are bonded to the Os3 core as separate ligands, and that under these conditions there is no ligand condensation.

AB - The reaction of the 'benzyne' cluster Os3H2(CO)9(C6H4) with diphenylacetylene affords the new compound Os3(CO)7(C6H4)[PhCC(H)Ph]2; a single crystal X-ray analysis of this product shows that two PhCC(H)Ph units and the benzyne moiety are bonded to the Os3 core as separate ligands, and that under these conditions there is no ligand condensation.

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DO - 10.1016/0022-328X(89)88086-6

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ER -

Reaction of Os₃H₂(CO)₉(C₆H₄) with diphenylacetylene: the formation and structural characterisation of Os₃(CO)₇(C₆H₄)[PhCC(H)Ph]₂

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