Reaction of Os3(CO)12 with ethylene under moderate pressure; The molecular structures of [Os4(CO)12(C2H2)] and [Os4(CO)12(C4H6)]

Ronald Jackson; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Stephen W. Sankey

doi:10.1016/S0022-328X(00)86085-4

Reaction of Os₃(CO)₁₂ with ethylene under moderate pressure; The molecular structures of [Os₄(CO)₁₂(C₂H₂)] and [Os₄(CO)₁₂(C₄H₆)]

Ronald Jackson, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Stephen W. Sankey

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of the ethylene with Os₃(CO)₁₂ in hexane, at 20 atmospheres pressure yields the known complex H₂Os₃(CO)₉C.CH₂, and two new tetranuclear clusters Os₄(CO)₁₂CH:CH (1) and Os₄(CO)₁₂(HC:CEt) (2) which have been characterised by X-ray crystallography.

Original language	English
Pages (from-to)	C1-C6
Journal	Journal of Organometallic Chemistry
Volume	193
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)86085-4
Publication status	Published - 31 Dec 1980

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)86085-4

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title = "Reaction of Os3(CO)12 with ethylene under moderate pressure; The molecular structures of [Os4(CO)12(C2H2)] and [Os4(CO)12(C4H6)]",

abstract = "The reaction of the ethylene with Os3(CO)12 in hexane, at 20 atmospheres pressure yields the known complex H2Os3(CO)9C.CH2, and two new tetranuclear clusters Os4(CO)12CH:CH (1) and Os4(CO)12(HC:CEt) (2) which have been characterised by X-ray crystallography.",

author = "Ronald Jackson and Johnson, \{Brian F.G.\} and Jack Lewis and Raithby, \{Paul R.\} and Sankey, \{Stephen W.\}",

year = "1980",

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AU - Jackson, Ronald

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Sankey, Stephen W.

PY - 1980/12/31

Y1 - 1980/12/31

N2 - The reaction of the ethylene with Os3(CO)12 in hexane, at 20 atmospheres pressure yields the known complex H2Os3(CO)9C.CH2, and two new tetranuclear clusters Os4(CO)12CH:CH (1) and Os4(CO)12(HC:CEt) (2) which have been characterised by X-ray crystallography.

AB - The reaction of the ethylene with Os3(CO)12 in hexane, at 20 atmospheres pressure yields the known complex H2Os3(CO)9C.CH2, and two new tetranuclear clusters Os4(CO)12CH:CH (1) and Os4(CO)12(HC:CEt) (2) which have been characterised by X-ray crystallography.

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ER -

Reaction of Os₃(CO)₁₂ with ethylene under moderate pressure; The molecular structures of [Os₄(CO)₁₂(C₂H₂)] and [Os₄(CO)₁₂(C₄H₆)]

Abstract

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