Reaction of [Os3(CO)10(NCMe)2] with amides and aldehydes; X-ray crystal structure of [Os3(CO)10(μ-H)(COCH2Ph)]

Brian F.G. Johnson; Jack Lewis; Timothy L. Odiaka; Paul R. Raithby

doi:10.1016/S0022-328X(00)85827-1

Reaction of [Os₃(CO)₁₀(NCMe)₂] with amides and aldehydes; X-ray crystal structure of [Os₃(CO)₁₀(μ-H)(COCH₂Ph)]

Brian F.G. Johnson, Jack Lewis, Timothy L. Odiaka, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [OS₃(CO)₁₀(NCMe)₂] with amides and aldehydes has provided a high-yield route to clusters of the type [OS₃(CO)₁₀H(NHCOR)] (R H, Me, Ph, Et, Pr) and [OS₃(CO)₁₀H(COR)] (R Me, Ph, CH₂Ph, C₆H₁₃), respectively; the molecular structure of [OS₃(CO)₁₀H(COCH₂Ph)] has been established by a single-crystal X-ray analysis.

Original language	English
Pages (from-to)	C56-C60
Journal	Journal of Organometallic Chemistry
Volume	216
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)85827-1
Publication status	Published - 25 Aug 1981

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)85827-1

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@article{f346bb9e4fab411db0fe9660efd209cb,

title = "Reaction of [Os3(CO)10(NCMe)2] with amides and aldehydes; X-ray crystal structure of [Os3(CO)10(μ-H)(COCH2Ph)]",

abstract = "Reaction of [OS3(CO)10(NCMe)2] with amides and aldehydes has provided a high-yield route to clusters of the type [OS3(CO)10H(NHCOR)] (R H, Me, Ph, Et, Pr) and [OS3(CO)10H(COR)] (R Me, Ph, CH2Ph, C6H13), respectively; the molecular structure of [OS3(CO)10H(COCH2Ph)] has been established by a single-crystal X-ray analysis.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Odiaka, \{Timothy L.\} and Raithby, \{Paul R.\}",

year = "1981",

month = aug,

day = "25",

doi = "10.1016/S0022-328X(00)85827-1",

language = "English",

volume = "216",

pages = "C56--C60",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Reaction of [Os3(CO)10(NCMe)2] with amides and aldehydes; X-ray crystal structure of [Os3(CO)10(μ-H)(COCH2Ph)]

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Odiaka, Timothy L.

AU - Raithby, Paul R.

PY - 1981/8/25

Y1 - 1981/8/25

N2 - Reaction of [OS3(CO)10(NCMe)2] with amides and aldehydes has provided a high-yield route to clusters of the type [OS3(CO)10H(NHCOR)] (R H, Me, Ph, Et, Pr) and [OS3(CO)10H(COR)] (R Me, Ph, CH2Ph, C6H13), respectively; the molecular structure of [OS3(CO)10H(COCH2Ph)] has been established by a single-crystal X-ray analysis.

AB - Reaction of [OS3(CO)10(NCMe)2] with amides and aldehydes has provided a high-yield route to clusters of the type [OS3(CO)10H(NHCOR)] (R H, Me, Ph, Et, Pr) and [OS3(CO)10H(COR)] (R Me, Ph, CH2Ph, C6H13), respectively; the molecular structure of [OS3(CO)10H(COCH2Ph)] has been established by a single-crystal X-ray analysis.

UR - http://www.scopus.com/inward/record.url?scp=0002464063&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)85827-1

DO - 10.1016/S0022-328X(00)85827-1

M3 - Article

AN - SCOPUS:0002464063

SN - 0022-328X

VL - 216

SP - C56-C60

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Reaction of [Os₃(CO)₁₀(NCMe)₂] with amides and aldehydes; X-ray crystal structure of [Os₃(CO)₁₀(μ-H)(COCH₂Ph)]

Abstract

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