Reaction of [M3(CO)12] (M = Ru or Os) with the chalconide elements; X-ray crystal and molecular structure of [Os 4(CO)12H2Se2]

Brian F.G. Johnson; Jack Lewis; Philip G. Lodge; Paul R. Raithby; Kim Henrick; Mary McPartlin

doi:10.1039/C39790000719

Reaction of [M₃(CO)₁₂] (M = Ru or Os) with the chalconide elements; X-ray crystal and molecular structure of [Os ₄(CO)₁₂H₂Se₂]

Brian F.G. Johnson
, Jack Lewis
, Philip G. Lodge
, Paul R. Raithby
, Kim Henrick
, Mary McPartlin

University of Cambridge
London Metropolitan University

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [Os₃(CO)₁₂] with X_n (X = S, Se, or Te) in n-octane under reflux yields [Os₃(CO)₉H ₂X], [Os₃(CO)₉X₂], and [Os ₄(CO)₁₂H₂X₂], but a CO/H₂ pressure of 35 atm is required to prepare the ruthenium analogues [Ru ₃(CO)₉H₂X] and [Ru₃(CO) ₉X₂]; an X-ray analysis of [Os₄(CO) ₁₂H₂Se₂] shows that it has a novel trigonal prismatic Os₄Se₂ core.

Original language	English
Pages (from-to)	719-720
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39790000719
Publication status	Published - 31 Dec 1979

ASJC Scopus subject areas

Molecular Medicine

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title = "Reaction of [M3(CO)12] (M = Ru or Os) with the chalconide elements; X-ray crystal and molecular structure of [Os 4(CO)12H2Se2]",

abstract = "Reaction of [Os3(CO)12] with Xn (X = S, Se, or Te) in n-octane under reflux yields [Os3(CO)9H 2X], [Os3(CO)9X2], and [Os 4(CO)12H2X2], but a CO/H2 pressure of 35 atm is required to prepare the ruthenium analogues [Ru 3(CO)9H2X] and [Ru3(CO) 9X2]; an X-ray analysis of [Os4(CO) 12H2Se2] shows that it has a novel trigonal prismatic Os4Se2 core.",

author = "Johnson, \{Brian F.G.\} and Jack Lewis and Lodge, \{Philip G.\} and Raithby, \{Paul R.\} and Kim Henrick and Mary McPartlin",

year = "1979",

month = dec,

day = "31",

doi = "10.1039/C39790000719",

language = "English",

pages = "719--720",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Reaction of [M3(CO)12] (M = Ru or Os) with the chalconide elements; X-ray crystal and molecular structure of [Os 4(CO)12H2Se2]

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Lodge, Philip G.

AU - Raithby, Paul R.

AU - Henrick, Kim

AU - McPartlin, Mary

PY - 1979/12/31

Y1 - 1979/12/31

N2 - Reaction of [Os3(CO)12] with Xn (X = S, Se, or Te) in n-octane under reflux yields [Os3(CO)9H 2X], [Os3(CO)9X2], and [Os 4(CO)12H2X2], but a CO/H2 pressure of 35 atm is required to prepare the ruthenium analogues [Ru 3(CO)9H2X] and [Ru3(CO) 9X2]; an X-ray analysis of [Os4(CO) 12H2Se2] shows that it has a novel trigonal prismatic Os4Se2 core.

AB - Reaction of [Os3(CO)12] with Xn (X = S, Se, or Te) in n-octane under reflux yields [Os3(CO)9H 2X], [Os3(CO)9X2], and [Os 4(CO)12H2X2], but a CO/H2 pressure of 35 atm is required to prepare the ruthenium analogues [Ru 3(CO)9H2X] and [Ru3(CO) 9X2]; an X-ray analysis of [Os4(CO) 12H2Se2] shows that it has a novel trigonal prismatic Os4Se2 core.

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DO - 10.1039/C39790000719

M3 - Article

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SN - 0022-4936

SP - 719

EP - 720

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -

Reaction of [M₃(CO)₁₂] (M = Ru or Os) with the chalconide elements; X-ray crystal and molecular structure of [Os ₄(CO)₁₂H₂Se₂]

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