Reaction of [(μ-H)Os3(CO)11]- anion with dioxygen

Christopher J. Cathey; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Wing Tak Wong

doi:10.1016/0022-328X(93)80171-7

Reaction of [(μ-H)Os₃(CO)₁₁]^- anion with dioxygen

Christopher J. Cathey, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, Wing Tak Wong

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The anion [(μ-H)Os₃(CO)₁₁]^- reacts with dioxygen in solution to give a yellow species which further reacts with Os₆(CO)₁₈ to yield [(μ-H)Os₃(CO)₁₀.(/gm₂-O₂C).Os₆(CO)₁₇]^-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.

Original language	English
Pages (from-to)	C12-C14
Journal	Journal of Organometallic Chemistry
Volume	450
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(93)80171-7
Publication status	Published - 18 May 1993

Funding

We thank the Science and Engineering Research Council (S.E.R.C.), I.C.I. plc (C.J.C.), the Royal Com-mision for the Exhibition of 1851, and the Committee of Vice-Chancellors and Principals (W.T.W) for financial support.

Funders	Funder number
I.C.I. plc
Royal Commission for the Exhibition of 1851
Engineering and Physical Sciences Research Council

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/0022-328X(93)80171-7

Cite this

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title = "Reaction of [(μ-H)Os3(CO)11]- anion with dioxygen",

abstract = "The anion [(μ-H)Os3(CO)11]- reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18 to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.",

author = "Cathey, {Christopher J.} and Johnson, {Brian F.G.} and Jack Lewis and Raithby, {Paul R.} and Wong, {Wing Tak}",

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AU - Cathey, Christopher J.

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Wong, Wing Tak

PY - 1993/5/18

Y1 - 1993/5/18

N2 - The anion [(μ-H)Os3(CO)11]- reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18 to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.

AB - The anion [(μ-H)Os3(CO)11]- reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18 to yield [(μ-H)Os3(CO)10.(/gm2-O2C).Os6(CO)17]-. The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.

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