Reaction chemistry of alkynes with the tris(acetonitrile)-ruthenium cluster [Ru3(CO)9(MeCN)3]

Andrew J. Edwards, Nicholas E. Leadbeater, Jack Lewis, Paul R. Raithby

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Abstract

The reaction of acetylene, monosubstituted alkynes HC2R (R = Ph and SiMe3) and disubstituted alkynes C2RR′ (R = R′ = Me or Ph, R = Me, R′ = Et) with the tris(acetonitrile)-substituted cluster [Ru3(CO)9(MeCN)3] have been studied. Monosubstituted alkynes form acetylide complexes [Ru3H(CO)9(C2R)] in high yield. Disubstituted alkynes undergo [2 + 2 + 2] cyclotrimerisation reaction to yield [Ru3(CO)93222-C6R3R′3)] complexes in good yield. These complexes contain an aromatic, face-capping, group co-ordinated to the triruthenium cluster.

Original languageEnglish
Pages (from-to)3785-3787
Number of pages3
JournalJournal of the Chemical Society, Dalton Transactions
Volume1995
Issue number23
DOIs
Publication statusPublished - 31 Dec 1995

ASJC Scopus subject areas

  • Chemistry(all)

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