Rapid carbonylative coupling reactions using palladium(I) dimers: applications to (CO)-C-11-radiolabelling for the synthesis of PET tracers

G Buscemi, P W Miller, Steven Kealey, A D Gee, N J Long, J Passchier, R Vilar

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Palladium dimers with sterically hindered phosphines have been shown to be excellent pre-catalysts for the aminocarbonylation of aryl halides to yield amides and one of them has been successfully employed as a pre-catalyst for the synthesis of C-11-radiolabelled amides for PET imaging.
Original languageEnglish
Pages (from-to)3499-3503
Number of pages5
JournalOrganic and Biomolecular Chemistry
Volume9
Issue number9
DOIs
Publication statusPublished - 2011

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Palladium
Carbon Monoxide
Amides
Dimers
amides
tracers
palladium
dimers
Phosphines
catalysts
Catalysts
synthesis
phosphines
halides
Imaging techniques

Cite this

Rapid carbonylative coupling reactions using palladium(I) dimers: applications to (CO)-C-11-radiolabelling for the synthesis of PET tracers. / Buscemi, G; Miller, P W; Kealey, Steven; Gee, A D; Long, N J; Passchier, J; Vilar, R.

In: Organic and Biomolecular Chemistry, Vol. 9, No. 9, 2011, p. 3499-3503.

Research output: Contribution to journalArticle

Buscemi, G ; Miller, P W ; Kealey, Steven ; Gee, A D ; Long, N J ; Passchier, J ; Vilar, R. / Rapid carbonylative coupling reactions using palladium(I) dimers: applications to (CO)-C-11-radiolabelling for the synthesis of PET tracers. In: Organic and Biomolecular Chemistry. 2011 ; Vol. 9, No. 9. pp. 3499-3503.
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